The Patricia Zn–Pb–Ag epithermal ore deposit: An uncommon type of mineralization in northeastern Chile

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dc.contributor.authorChinchilla Benavides, Darío
dc.contributor.authorOrtega Menor, Lorena
dc.contributor.authorPiña García, Rubén
dc.contributor.authorMerinero Palomares, Raúl
dc.contributor.authorMoncada, Daniel
dc.contributor.authorBodnar, Robert J.
dc.contributor.authorQuesada Ochoa, Cecilio
dc.contributor.authorValverde, Antonio
dc.contributor.authorLunar Hernández, María Del Rosario
dc.date.accessioned2023-06-18T05:56:39Z
dc.date.available2023-06-18T05:56:39Z
dc.date.issued2016-03
dc.description.abstractThe Patricia ore deposit represents an unusual example of economic Zn–Pb–Ag mineralization at the northernmost end of the Late Eocene–Oligocene metallogenic belt in Chile. It is hosted by volcano-sedimentary units, which are typically tuffaceous and andesitic breccias. The ore body consists of a set of subvertical E-W vein systems developed under a sinistral strike-slip regime that included transtensive domains with generalized extensional structures where the ores were deposited. The deposit is divided into two blocks by a set of NNW-ESE-trending reverse faults, which uplifted the eastern block and exhumed thicker and deeper parts of the deposit. At least 200 m of volcano-sedimentary pile hosting the mineralization has been eroded in this block. By contrast, the western block exposes a shallower part of the system where cherts, amorphous silica and jasperoids occur. Three main stages of mineralization have been defined: (1) pre-ore stage is characterized by early quartz, pyrite and arsenopyrite, (2) base-metal and silver stage; characterized by sphalerite (6 to 15 mol% FeS), galena, chalcopyrite, pyrrhotite and Ag-bearing minerals (freibergite, polybasite, stephanite, pyrargyrite, freieslebenite and acanthite) and (3) post-ore stage; characterized by late quartz, kutnohorite and minor sulfides (arsenopyrite, sphalerite, pyrite, galena, Ag-bearing minerals and Pb-sulfosalts). Whole-ore geochemistry shows two groups of elements that are positively correlated; 1) Ag–Cd–Cu–Pb–Zn related to the base metal sulfides and 2) Au–As–Ge–Sb–W related to arsenopyrite and pyrite. Hydrothermal alteration is pervasive in the outcropping mineralized areas, including silicification and locally, vuggy silica textures. At depth, chloritic and sericitic alteration is developed along vein selvages and is superimposed to the regional propylitic alteration. Fluid inclusions indicate that the base-metal ores were deposited from 250 to 150 °C moderate salinity fluids (1–9 wt.% NaCl). The pre-ore stage is characterized by a saline fluid (6–22 wt.% NaCl) and between 210 and 250 °C whereas the post-ore stage has salinity of 4–8 wt.% and temperature from 175 to 215 °C. Cooling was the mechanism of ore mineral precipitation in the Patricia deposit, although mixing of fluids could have occurred in the pre-ore stage. Mineralogical, geochemical and fluid inclusion evidence is consistent with an intermediate sulfidation (IS) epithermal deposit type. This study highlights the high potential for hidden economic mineralization at depth in the western block and for extension of the ore body both to the south and to deeper levels in the eastern block of the Patricia ore deposit. To a larger extent, the implications of finding such polymetallic epithermal style of mineralization in the northern Chile Precordillera is relevant both to the regional metallogenic perspective and to the exploration potential of the region, where the late Eocene–early Oligocene metallogenic belt apparently disappears.
dc.description.departmentDepto. de Mineralogía y Petrología
dc.description.facultyFac. de Ciencias Geológicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Economía y Competitividad (MINECO)
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/56047
dc.identifier.doi10.1016/j.oregeorev.2015.10.026
dc.identifier.issn0169-1368
dc.identifier.officialurlhttps://www.sciencedirect.com/journal/ore-geology-reviews/vol/73/part/P1
dc.identifier.relatedurlhttp://journal homepage: www.elsevier.com/locate/oregeorev www.elsevier.com/locate/oregeorev
dc.identifier.urihttps://hdl.handle.net/20.500.14352/23635
dc.journal.titleOre Geology Reviews
dc.language.isoeng
dc.page.final126
dc.page.initial104
dc.publisherElsevier
dc.relation.projectIDCGL2010 – 17668
dc.rights.accessRightsrestricted access
dc.subject.cdu548
dc.subject.keywordIntermediate-sulfidation
dc.subject.keywordAg-sulfosalts
dc.subject.keywordOpen-space filling
dc.subject.keywordPolymetallic epithermal
dc.subject.keywordStrike-slip duplex
dc.subject.keywordDomeyko fault system
dc.subject.keywordMetallogenic belt
dc.subject.ucmCristalografía (Geología)
dc.titleThe Patricia Zn–Pb–Ag epithermal ore deposit: An uncommon type of mineralization in northeastern Chile
dc.typejournal article
dc.volume.number73
dspace.entity.typePublication
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relation.isAuthorOfPublication.latestForDiscovery8f9c3c60-ec8b-4cd1-b34a-8f6ff0133383
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