Synthesis and self-assembly of a carboranecontaining ABC triblock terpolymer: morphology control on a dual-stimuli responsive system

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dc.contributor.authorFernáncez Alvarez, Roberto
dc.contributor.authorHlavatovicová, Eva
dc.contributor.authorRodzén, Krzysztof
dc.contributor.authorStrachota, Adam
dc.contributor.authorKereïche, Sami
dc.contributor.authorMatejicek, Pavel
dc.contributor.authorCabrera González, Justo Enrique
dc.contributor.authorNúñez, Rosario
dc.contributor.authorUchman, Mariusz
dc.date.accessioned2024-02-05T12:26:59Z
dc.date.available2024-02-05T12:26:59Z
dc.date.issued2019
dc.description.abstractAmphiphilic triblock terpolymers have attractive applications in the preparation of nanoparticles with controlled morphology. An additional level of morphology control can be provided by reactive blocks, whose interactions with the solvent vary under different stimuli. In this work, we synthesized a triblock terpolymer (poly(acrylic acid)-b-poly(4-hydroxystyrene)-b-poly{1-[4-(1-methyl-1,2-dicarba-closo-dodecaborane-2-yl methyl)-phenyl]ethylene}) (PAA-b-PHS-b-PSC) containing carboranes as pendant groups by reversible addition fragmentation chain transfer (RAFT) polymerization and subsequently studied its behavior in aqueous solution. Once the nanoparticles were formed, the solubility of the second and third blocks was changed via pH and CsF reactions, respectively. The resulting micelles work as an ON/OFF system, using changes in fluorescence intensity at different pH values.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipCzech Science Foundation
dc.description.sponsorshipMinisterio de Economía y Competitividad (España)
dc.description.sponsorshipGeneralitat de Catalunya
dc.description.statuspub
dc.identifier.citationFernandez-Alvarez, Roberto, et al. «Synthesis and Self-Assembly of a Carborane-Containing ABC Triblock Terpolymer: Morphology Control on a Dual-Stimuli Responsive System». Polymer Chemistry, vol. 10, n.o 22, 2019, pp. 2774-80. https://doi.org/10.1039/C9PY00518
dc.identifier.doi10.1039/c9py00518h
dc.identifier.essn1759-9962
dc.identifier.issn1759-9954
dc.identifier.officialurlhttps://doi.org/10.1039/c9py00518h
dc.identifier.urihttps://hdl.handle.net/20.500.14352/98921
dc.issue.number22
dc.journal.titlePolymer Chemistry
dc.language.isoeng
dc.page.final2780
dc.page.initial2774
dc.publisherRoyal Society of Chemistry
dc.relation.projectIDGrant No. 17-00289Y
dc.relation.projectID(CTQ2016-75150-R9)
dc.relation.projectID(2017/SGR/ 1720)
dc.rights.accessRightsmetadata only access
dc.subject.cdu547
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco23 Química
dc.titleSynthesis and self-assembly of a carboranecontaining ABC triblock terpolymer: morphology control on a dual-stimuli responsive system
dc.typejournal article
dc.volume.number10
dspace.entity.typePublication
relation.isAuthorOfPublication5fdca92d-6eb3-4245-bdfe-1bf73af9881b
relation.isAuthorOfPublication.latestForDiscovery5fdca92d-6eb3-4245-bdfe-1bf73af9881b
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