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FTIR-ATR detection method for emerging C3-plants-derivated adulterants in honey: Beet, dates, and carob syrups

dc.contributor.authorCárdenas Escudero, Jafet
dc.contributor.authorGalán Madruga, David
dc.contributor.authorCáceres, Jorge Omar
dc.date.accessioned2024-07-05T11:04:15Z
dc.date.available2024-07-05T11:04:15Z
dc.date.issued2023-12
dc.description.abstractThe European Union Publications Office has recently presented a report on the European Union’s coordinated action with the Joint Research Centre to determine certain fraudulent practices in the honey sector, in which it has been indicated that 74% of the samples analyzed, imported from China, and 93% of the samples analyzed, imported from Turkey, the two largest honey producers worldwide, presented at least one indicator of exogenous sugar or suspicion of being adulterated. This situation has revealed the critical state of the problem of honey adulteration worldwide and the need to develop analytical techniques for its detection. Even though the adulteration of honey is carried out in a general way with sweetened syrups derived from C4 plants, recent studies have indicated the emerging use of syrups derived from C3 plants for the adulteration of honey. This kind of adulteration makes it impossible to analyze its detection using official analysis techniques. In this work, we have developed a fast, simple, and economical method based on the Fourier transform infrared spectroscopy technique, with attenuated total reflectance, for the qualitative, quantitative, and simultaneous determination of beetroot, date, and carob syrups, derived from of C3 plants; whose available bibliography is very scarce and analytically not very conclusive for its use by the authorities. The proposed method has been based on the establishment of the spectral differences between honey and the mentioned syrups at eight different points in the spectral region between 1200 and 900 cm− 1 of the mid-infrared, characteristic of the vibrational modes of carbohydrates in honey, which allows the pre-discrimination of the presence or absence of the syrups studied, and their subsequent quantification, with precision levels lower than 2.0% of the relative standard deviation and relative errors lower than 2.0% (m/m).en
dc.description.departmentDepto. de Química Analítica
dc.description.facultyFac. de Ciencias Químicas
dc.description.fundingtypeDescuento UCM
dc.description.refereedTRUE
dc.description.statuspub
dc.identifier.citationJ. Cárdenas-Escudero, D. Galán-Madruga, J.O. Cáceres, FTIR-ATR detection method for emerging C3-plants-derivated adulterants in honey: Beet, dates, and carob syrups, Talanta, Volume 265, 2023, 124768,
dc.identifier.doi10.1016/j.talanta.2023.124768
dc.identifier.issn0039-9140
dc.identifier.officialurlhttps://doi.org/10.1016/j.talanta.2023.124768
dc.identifier.relatedurlhttps://www.sciencedirect.com/science/article/pii/S0039914023005192
dc.identifier.urihttps://hdl.handle.net/20.500.14352/105695
dc.issue.number124768
dc.journal.titleTalanta
dc.language.isoeng
dc.publisherElsevier
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.cdu543
dc.subject.keywordPure honey
dc.subject.keywordHoney adulterants
dc.subject.keywordBeet syrup
dc.subject.keywordDate syrup
dc.subject.keywordCarob syrup
dc.subject.keywordFourier transformed infrared spectroscopy
dc.subject.ucmQuímica
dc.subject.ucmQuímica analítica (Química)
dc.subject.unesco23 Química
dc.subject.unesco2301 Química Analítica
dc.titleFTIR-ATR detection method for emerging C3-plants-derivated adulterants in honey: Beet, dates, and carob syrupsen
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number265
dspace.entity.typePublication
relation.isAuthorOfPublicationbf2a48e5-d90f-4088-b628-d36248a10b76
relation.isAuthorOfPublication.latestForDiscoverybf2a48e5-d90f-4088-b628-d36248a10b76

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