Microwave and solvothermal methods for the synthesis of nickel and ruthenium complexes with 9-anthracene carboxylate ligand

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dc.contributor.authorCortijo Montes, Miguel
dc.contributor.authorDelgado-Martínez, Patricia
dc.contributor.authorGonzález Prieto, Rodrigo
dc.contributor.authorHerrero Domínguez, Santiago
dc.contributor.authorJiménez Aparicio, Reyes
dc.contributor.authorPerles Hernáez, Josefina
dc.contributor.authorPriego Bermejo, José Luis
dc.contributor.authorTorres, Marisa Rosario
dc.date.accessioned2024-01-12T16:46:30Z
dc.date.available2024-01-12T16:46:30Z
dc.date.issued2015
dc.description.abstractMicrowave and solvothermal activation processes have been explored as tools for the preparation of various nickel and ruthenium complexes. Different reaction conditions are tested using ethanol or water as solvents. Three nickel derivatives, [Ni(9-atc)2(OH2)2(py)2]·2EtOH (1), [Ni2(9-atc)4(OH2)(py)4]·2H2O (2·2H2O), and [Ni2(9-atc)4(py)2] (3), and two diruthenium compounds, {[Ru2Cl(9-atc)4]·2H2O}n (4) and [Ru2(9-atc)4(EtOH)2]·2EtOH (5), are obtained. The crystal structure determination of complexes 1-3 and 5 is also described. Compound 1 displays a 1D extended supramolecular structure with hydrogen bonds involving crystallization solvent molecules. Compound 2 is dimetallic, and both nickel centers show an octahedral coordination environment, whereas complexes 3 and 5 display a typical carboxylate-bridged paddlewheel-type structure with two metal atoms connected by four bridging carboxylate ligands. All compounds show weak antiferromagnetic interactions except 3, where a strong intra-dimer antiferromagnetic coupling is observed. Compound 4 also shows a strong zero field splitting.
dc.description.departmentDepto. de Química Inorgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Economía y Competitividad (España)
dc.description.sponsorshipComunidad de Madrid
dc.description.statuspub
dc.identifier.citationCortijo, M., Delgado-Martínez, P., González-Prieto, R., Herrero, S., Jiménez-Aparicio, R., Perles, J., Priego, J. L., & Torres. (2015). Microwave and solvothermal methods for the synthesis of nickel and ruthenium complexes with 9-anthracene carboxylate ligand. Inorganica Chimica Acta, 424, 176-185. https://doi.org/10.1016/J.ICA.2014.07.063
dc.identifier.doi10.1016/j.ica.2014.07.063
dc.identifier.issn0020-1693
dc.identifier.officialurlhttps://doi.org/10.1016/J.ICA.2014.07.063
dc.identifier.urihttps://hdl.handle.net/20.500.14352/92884
dc.journal.titleInorganica Chimica Acta
dc.language.isoeng
dc.page.final185
dc.page.initial176
dc.publisherElsevier
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.accessRightsrestricted access
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.cdu546
dc.subject.keywordMicrowave
dc.subject.keywordSolvothermal
dc.subject.keywordNickel
dc.subject.keywordRuthenium
dc.subject.keywordDinuclear
dc.subject.keywordMagnetism
dc.subject.ucmQuímica
dc.subject.unesco2303 Química Inorgánica
dc.titleMicrowave and solvothermal methods for the synthesis of nickel and ruthenium complexes with 9-anthracene carboxylate ligand
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number424
dspace.entity.typePublication
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