Publication:
3D solid supported inter-polyelectrolyte complexes obtained by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate)

dc.contributor.authorGuzmán, Eduardo
dc.contributor.authorMaestro, Armando
dc.contributor.authorLlamas, Sara
dc.contributor.authorÁlvarez-Rodríguez, Jesús
dc.contributor.authorOrtega, Francisco
dc.contributor.authorMaroto-Valiente, Ángel
dc.contributor.authorGonzález Rubio, Ramón
dc.date.accessioned2023-06-18T06:50:03Z
dc.date.available2023-06-18T06:50:03Z
dc.date.issued2016-02-05
dc.description.abstractThis work addresses the formation and the internal morphology of polyelectrolyte layers obtained by the layer-by-layer method. A multimodal characterization showed the absence of stratification of the films formed by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate). Indeed the final organization might be regarded as threedimensional solid-supported inter-polyelectrolyte films. The growth mechanism of the multilayers, followed using a quartz crystal microbalance, evidences two different growth trends, which show a dependency on the ionic strength due to its influence onto the polymer conformation. The hydration state does not modify the multilayer growth, but it contributes to the total adsorbed mass of the film. The water associated with the polyelectrolyte films leads to their swelling and plastification. The use of X-ray photoelectron spectroscopy has allowed for deeper insights on the internal structure and composition of the polyelectrolyte multilayers.
dc.description.departmentDepto. de Química Física
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Economía y Competitividad (MINECO)
dc.description.sponsorshipESA
dc.description.sponsorshipEU
dc.description.sponsorshipESFCOST
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/35747
dc.identifier.doi10.3762/bjnano.7.18
dc.identifier.issn2190-4286
dc.identifier.officialurlhttp://www.beilstein-journals.org/bjnano/content/pdf/2190-4286-7-18.pdf
dc.identifier.relatedurlhttps://www.beilstein-journals.org/bjnano/single/articleFullText.htm?publicId=2190-4286-7-18&vt=f&tpn=0&bpn=home
dc.identifier.urihttps://hdl.handle.net/20.500.14352/24348
dc.journal.titleBeilstein Journal of Nanotechnoly
dc.language.isoeng
dc.page.final208
dc.page.initial197
dc.publisherBeilstein-Institut zur Förderung der Chemischen Wissenschaften
dc.relation.projectIDFIS 2012-28231-C02-01
dc.relation.projectIDFIS 2014-62005-EXP
dc.relation.projectIDFASES and PASTA
dc.relation.projectIDMarie Curie ITN-CoWet
dc.relation.projectIDCM1101 and MP1106
dc.rightsAtribución 3.0 España
dc.rights.accessRightsopen access
dc.rights.urihttps://creativecommons.org/licenses/by/3.0/es/
dc.subject.cdu544
dc.subject.keywordcharge compensation
dc.subject.keywordhydration
dc.subject.keywordpolyelectrolyte multilayers
dc.subject.keywordstratification
dc.subject.keywordswelling
dc.subject.ucmFísica (Física)
dc.subject.ucmFísica de materiales
dc.subject.ucmQuímica física (Física)
dc.subject.ucmFísica (Química)
dc.subject.ucmQuímica física (Química)
dc.subject.unesco22 Física
dc.subject.unesco2210 Química Física
dc.title3D solid supported inter-polyelectrolyte complexes obtained by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate)
dc.typejournal article
dc.volume.number7
dspace.entity.typePublication
relation.isAuthorOfPublicationffe9a2c2-caca-446f-a49e-14cacb7984df
relation.isAuthorOfPublication.latestForDiscoveryffe9a2c2-caca-446f-a49e-14cacb7984df
Files
Original bundle
Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
BeilsteinJ.pdf
Size:
783.87 KB
Format:
Adobe Portable Document Format
Collections