Catalyst-free insertion of carbon monoxide into terminal Mg–C(sp3) bonds

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dc.contributor.authorKubisz, M.
dc.contributor.authorFernández López, Israel
dc.contributor.authorHadlington, T. J.
dc.date.accessioned2026-04-21T06:51:10Z
dc.date.available2026-04-21T06:51:10Z
dc.date.issued2026-03-07
dc.description.abstractWe describe the catalyst-free Insertion of carbon monoxide (CO) into magnesium alkyl bonds, leading exclusively to enediolate compounds through C–C coupling. Computational investigations suggest a metallated ketene intermedate. Ultimately, the formed enedoliate fragment can be liberated on reaction with a silane, establishing a potential pathway for s-block metal alkyl formylation catalysis.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia e Inovación (España)
dc.description.sponsorshipAgencia Estatal de Investigación (España)
dc.description.statuspub
dc.identifier.citationKubisz, M., et al. «Catalyst-Free Insertion of Carbon Monoxide into Terminal Mg–C(Sp3 ) Bonds». Chemical Communications, vol. 62, n.o 29, 2026, pp. 7519-23. DOI.org (Crossref), https://doi.org/10.1039/D6CC00736H.
dc.identifier.doi10.1039/d6cc00736h
dc.identifier.officialurlhttps://doi.org/10.1039/D6CC00736H
dc.identifier.relatedurlhttps://pubs.rsc.org/en/content/articlelanding/2026/cc/d6cc00736h
dc.identifier.urihttps://hdl.handle.net/20.500.14352/134908
dc.journal.titleChemical Communications
dc.language.isoeng
dc.page.initial7519
dc.publisherRSC
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2022-139318NB-I00/ES/ENTENDIENDO LOS FACTORES QUE CONTROLAN LA REACTIVIDAD EN GRUPOS PRINCIPALES/
dc.relation.projectIDProject 101076897 – SINGAMBI
dc.relation.projectIDProject Nr. 523956566
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.cdu547
dc.subject.ucmQuímica
dc.subject.unesco23 Química
dc.titleCatalyst-free insertion of carbon monoxide into terminal Mg–C(sp3) bonds
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number62
dspace.entity.typePublication
relation.isAuthorOfPublicationb2a789aa-d9bf-4564-b0e2-35b8de8d6d06
relation.isAuthorOfPublication.latestForDiscoveryb2a789aa-d9bf-4564-b0e2-35b8de8d6d06

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