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Mn3MnNb2O9: high-pressure triple perovskite with 1 : 2 B-site order and modulated spins

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Mn4Nb2O9_ChemCommRevised.pdf (618.38 KB)

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https://doi.org/10.1039/D1CC02782D

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2021

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https://hdl.handle.net/20.500.14352/137076

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14. E. Solana-Madruga, C. Ritter, C. Aguilar-Maldonado, O. Mentré, J. P. Attfield, A. M. Arévalo-López. Mn3MnNb2O9: high-pressure triple perovskite with 1 : 2 B-site order and modulated spins. Chem. Commun. 2021, 57, 8441-8444. doi: 10.1039/d1cc02782d

Abstract

The first triple perovskite with Mn in A- and 1 : 2 B-site order Mn3MnNb2O9, prepared using high pressure phase transformation of the magnetodielectric Mn4Nb2O9, is reported herein. It has a complex magnetic behaviour with a transition from a collinear AFM into an evolving incommensurate spin density wave (SDW) further stabilised into a lock-in structure dictated by the B-site order.

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Química inorgánica (Química)

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2303 Química Inorgánica

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