Phenol photodegradation with oxygen and hydrogen peroxide over TiO2 and Fe-doped TiO2

Abstract

Photodegradation of phenol was investigated with two types of oxidant agents in water, oxygen and hydrogen peroxide, at two different reaction pH with a series of nanosized iron-doped anatase TiO2 catalysts with different iron contents. The catalysts have been prepared by a sol–gel/microemulsion method. Firstly, iron-doped titania catalysts were studied with respect to their activity behavior when oxygen was used as oxidant agent in the photocatalytic degradation of aqueous phenol in comparison with un-doped reference catalysts. Secondly, two catalysts (TiO2 and 0.7 wt.% Fe-doped TiO2) were selected to extend the study for the employment of hydrogen peroxide as oxidant at different concentrations and two initial reaction pHs. An enhancement of the photocatalytic activity is observed only for relatively low doping level (ca. 0.7 wt.%) in catalyst calcined at 450 °C preferably using hydrogen peroxide as oxidant agent which is attributable to the partial introduction of Fe3+ cations into the anatase structure. Nevertheless, it has been demonstrated that catalyst surface properties can play an important role during phenol photodegradation process on the basis of the analysis of differences found in the photoactivity as a function of reaction pH.