Synthesis and electropolymerization of a perylenebisimide-functionalized 3,4-ethylenedioxythiophene (EDOT) derivative
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2005
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American Chemical Society
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Synthesis and Electropolymerization of a Perylenebisimide-Functionalized 3,4-Ethylenedioxythiophene (EDOT) Derivative José L. Segura, Rafael Gómez, Egon Reinold, and Peter Bäuerle Organic Letters 2005 7 (12), 2345-2348 DOI: 10.1021/ol050573m
Abstract
We have developed a convenient and straightforward procedure for the preparation of functionalized 3,4-ethylenedioxythiophene (EDOT) systems by using a new chloromethyl-EDOT derivative as a versatile synthon. Based on this procedure, novel suitably functionalized perylenetetracarboxylic diimide (PDI) dye derivatives covalently linked to 3,4-ethylenedioxythiophene moieties have been synthesized and electrochemically polymerized to yield a donor-acceptor PEDOT derivative with an enhanced absorption cross-section