Experimental study on marly clay stabilization under short-term conditions using volcanic ash and reactivity-controlled lime as activator

Abstract

Expansive soils undergo significant volume changes with moisture fluctuations, posing persistent challenges for infrastructure due to heave, settlement, and loss of bearing capacity. Stabilization is a common mitigation strategy, though traditional binders, such as cement and lime, are associated with high energy consumption and considerable CO2 emissions. In this context, identifying low-carbon alternatives is essential. This study evaluates the short-term behavior of expansive marly clays from southern Spain stabilized with volcanic ash generated during the 2021 Tajogaite eruption (La Palma, Canary Islands, Spain). Volcanic ash was incorporated in different proportions to assess its performance as a natural pozzolan, while natural hydrated lime was used both as a direct stabilizer and as an activator to enhance ash reactivity. A key methodological contribution of this research is the monitoring of lime reactivity throughout storage, using XRD and TGA to quantify portlandite loss and partial carbonation before mixing—an aspect seldom addressed in stabilization studies. The experimental program included chemical and mineralogical characterization, compaction, Atterberg limits, free swelling, unconfined compressive strength, and direct shear tests on natural and stabilized mixtures. The results show that volcanic ash, particularly when lime-activated, substantially improves volumetric stability. Free swelling decreased from 11.9% in the natural soil to values as low as 1.7%, while dry density increased and plasticity decreased. Strength gains were modest under short-term conditions, consistent with the limited time for pozzolanic reactions to develop. The combined use of volcanic ash and lime reduced the lime demand required to achieve equivalent volumetric control, offering an eco-efficient and technically viable alternative for stabilizing expansive marly clays.