Salt diffusion through cation-exchange membranes in alcohol-water solutions
| dc.contributor.author | Izquierdo Gil, María Amparo | |
| dc.contributor.author | Barragán García, Vicenta María | |
| dc.contributor.author | Godino Gómez, María Paz | |
| dc.contributor.author | García Villaluenga, Juan Pedro | |
| dc.contributor.author | Ruiz Bauzá, Carlos | |
| dc.contributor.author | Seoane Rodríguez, Benjamín | |
| dc.date.accessioned | 2023-06-20T03:31:42Z | |
| dc.date.available | 2023-06-20T03:31:42Z | |
| dc.date.issued | 2009-01-12 | |
| dc.description | © 2008 Elsevier B.V. The authors of this study gratefully acknowledge Prof. C. Larchet and Prof. V. Nikonenko for donating MK40 membrane samples. Financial support from Comunidad de Madrid and Universidad Complutense de Madrid under Project CCG06-UCM/MAT-1037 is also gratefully acknowledged. | |
| dc.description.abstract | The salt flow through several commercial cation-exchange membranes separating two NaCl alcohol-water solutions with the same alcohol concentration, but different NaCl concentration was investigated. Homogeneous (Nafion-115) and heterogeneous (MK-40 and CR65-AZL-412) membranes were used in this work. The integral permeability coefficient was determined from the temporal evolution of the concentration in the dilute solution. The results showed that the integral permeability coefficient depends on both the solution alcohol concentration and the type of alcohol. It is observed that this dependence is function of the membrane structure. In general, for the heterogeneous membranes, the integral permeability coefficient is less sensible to alcohol concentration than for the homogeneous membrane at low and intermediate values of the alcohol percentage in the solutions. | |
| dc.description.department | Depto. de Estructura de la Materia, Física Térmica y Electrónica | |
| dc.description.faculty | Fac. de Ciencias Físicas | |
| dc.description.refereed | TRUE | |
| dc.description.sponsorship | Comunidad de Madrid | |
| dc.description.sponsorship | Universidad Complutense de Madrid | |
| dc.description.status | pub | |
| dc.eprint.id | https://eprints.ucm.es/id/eprint/20614 | |
| dc.identifier.doi | 10.1016/j.seppur.2008.10.017 | |
| dc.identifier.issn | 1383-5866 | |
| dc.identifier.officialurl | http://dx.doi.org/10.1016/j.seppur.2008.10.017 | |
| dc.identifier.relatedurl | http://pdn.sciencedirect.com/ | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14352/43725 | |
| dc.issue.number | 3 | |
| dc.journal.title | Separation and Purification Technology | |
| dc.language.iso | eng | |
| dc.page.final | 325 | |
| dc.page.initial | 321 | |
| dc.publisher | Elsevier Science BV | |
| dc.relation.projectID | CCG06-UCM/MAT-1037 | |
| dc.rights.accessRights | restricted access | |
| dc.subject.cdu | 536 | |
| dc.subject.keyword | Methanol Fuel-Cells | |
| dc.subject.keyword | Nonstationary Diffusion | |
| dc.subject.keyword | Transport-Properties | |
| dc.subject.keyword | Nafion Membranes | |
| dc.subject.keyword | Electrolyte | |
| dc.subject.keyword | Coefficients | |
| dc.subject.keyword | Potentials | |
| dc.subject.keyword | Behavior | |
| dc.subject.keyword | Volumes | |
| dc.subject.keyword | Nacl. | |
| dc.subject.ucm | Termodinámica | |
| dc.subject.unesco | 2213 Termodinámica | |
| dc.title | Salt diffusion through cation-exchange membranes in alcohol-water solutions | |
| dc.type | journal article | |
| dc.volume.number | 64 | |
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