Cathodoluminescence microscopy of superconducting and non-superconducting Tl_2Ba_2CuO_(6+ δ) polycrystals

dc.contributor.authorDíaz-Guerra Viejo, Carlos
dc.contributor.authorPiqueras De Noriega, Francisco Javier
dc.contributor.authorOpagiste, C.
dc.date.accessioned2023-06-20T19:05:42Z
dc.date.available2023-06-20T19:05:42Z
dc.date.issued1996-03-01
dc.description© 1996 Elsevier Science B.V. CDG acknowledges MEC for a FPI research grant. This work has been supported by DGICYT (Project PB93-1256).
dc.description.abstractLuminescence properties of Tl_2Ba_2CuO_(6+ δ) samples with different superconducting transition temperatures have been studied by cathodoluminescence (CL) in the scanning electron microscope. Independent of the crystal structure, tetragonal or orthorhombic, the Cl spectra show two resolved bands at about 430 nm (2.9 eV) and 540 nm (2.3 eV), respectively. The results show that the 2.3 eV emission is related to oxygen content and is more intense in low-oxygen content superconducting samples. It is proposed that this band is related to a complex center involving oxygen vacancies. A comparison of spectra from Tl_2Ba_2CuO_(6+ δ) and from precursors used in the synthesis (CuO_x, Tl_2Ba_2O_5) has been carried out.
dc.description.departmentDepto. de Física de Materiales
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipDGICYT
dc.description.sponsorshipMEC
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/26802
dc.identifier.doi10.1016/0921-4534(96)00055-X
dc.identifier.issn0921-4534
dc.identifier.officialurlhttp://dx.doi.org/10.1016/0921-4534(96)00055-X
dc.identifier.relatedurlhttp://www.sciencedirect.com
dc.identifier.relatedurlhttps://hal.archives-ouvertes.fr
dc.identifier.urihttps://hdl.handle.net/20.500.14352/59237
dc.issue.number1-feb
dc.journal.titlePhysica C
dc.language.isoeng
dc.page.final130
dc.page.initial121
dc.publisherElsevier Science BV
dc.relation.projectIDPB93-1256
dc.rights.accessRightsrestricted access
dc.subject.cdu538.9
dc.subject.keywordScanning Electron-Microscope
dc.subject.keywordHigh-Tc Superconductors
dc.subject.keywordCu-O
dc.subject.keywordYBa_2Cu_3O_(7-X)
dc.subject.keywordLuminescence
dc.subject.keywordPhase
dc.subject.keywordFilms
dc.subject.keywordTl_2Ba_2Cu_1O_6
dc.subject.ucmFísica de materiales
dc.titleCathodoluminescence microscopy of superconducting and non-superconducting Tl_2Ba_2CuO_(6+ δ) polycrystals
dc.typejournal article
dc.volume.number259
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