Rational molecular design enhancing the photonic performance of red-emitting perylene bisimide dyes

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dc.contributor.authorAvellanal Zaballa, Edurne
dc.contributor.authorDurán Sampedro, Gonzalo
dc.contributor.authorPrieto Castañeda, Alejandro
dc.contributor.authorRodríguez Agarrabeitia, Antonia
dc.contributor.authorGarcía Moreno, Inmaculada
dc.contributor.authorLópez Arbeloa, Íñigo María
dc.contributor.authorBañuelos Prieto, Jorge
dc.contributor.authorOrtiz García, María Josefa
dc.date.accessioned2023-06-17T22:09:28Z
dc.date.available2023-06-17T22:09:28Z
dc.date.copyrightThe article was received on 14 Mar 2017, accepted on 25 Apr 2017 and first published on 25 Apr 2017en
dc.date.issued2017-04-25
dc.description.abstractWe report the synthesis of novel multichromophoric organic architectures, where perylene red is decorated with BODIPY and/or hydroxycoumarin dyes acting as light harvesters and energy donors. The computationally-aided photophysical study of these molecular assemblies reveals a broadband absorption which, regardless of the excitation wavelength, leads solely to a bright red-edge emission from perylene bisimide after efficient intramolecular energy transfer hops. The increase of the absorbance of these molecular antennas at key pumping wavelengths enhances the laser action of the commercial perylene red. The herein applied strategy based on energy transfer dye lasers should boost the use of perylene-based dyes as active media for red-emitting lasers.en
dc.description.departmentSección Deptal. de Química Orgánica (Óptica y Optometría)
dc.description.facultyFac. de Óptica y Optometría
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia, Innovación y Universidades (España)
dc.description.sponsorshipGobierno Vasco
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/44993
dc.identifier.citationAvellanal-Zaballa, E., Durán Sampedro, G., Proeto Castañeda, A. et al. «Rational Molecular Design Enhancing the Photonic Performance of Red-Emitting Perylene Bisimide Dyes». Physical Chemistry Chemical Physics, vol. 19, n.o 20, mayo de 2017, pp. 13210-18. pubs.rsc.org, https://doi.org/10.1039/C7CP01626C.
dc.identifier.doi10.1039/C7CP01626C
dc.identifier.issn1463-9076
dc.identifier.officialurlhttp://dx.doi.org/10.1039/c7cp01626c
dc.identifier.relatedurlhttp://pubs.rsc.org/en/content/articlelanding/2017/cp/c7cp01626c#!divAbstract
dc.identifier.urihttps://hdl.handle.net/20.500.14352/18148
dc.issue.number20
dc.journal.titlePhysical Chemistry Chemical Physics
dc.language.isoeng
dc.page.final13218
dc.page.initial13210
dc.publisherRoyal Society of Chemistry
dc.relation.projectIDMAT2014-51937-C3-1-P
dc.relation.projectIDMAT2014-51937-C3-2-P
dc.relation.projectIDMAT2014-51937-C3-3-P
dc.relation.projectIDMAT2015- 68837-REDT
dc.relation.projectIDIT912-16
dc.rights.accessRightsrestricted access
dc.subject.cdu547.1
dc.subject.cdu539.19
dc.subject.cdu535.374
dc.subject.keywordMolecular design
dc.subject.keywordMultichromophoric organic aechitectures
dc.subject.keywordBODIPY
dc.subject.keywordPerylene red
dc.subject.keywordLight harvesters
dc.subject.keywordRed-emitting lasers
dc.subject.keywordMolecular antennas
dc.subject.ucmOptica (Química)
dc.subject.ucmQuímica orgánica (Química)
dc.subject.ucmLáseres
dc.subject.unesco2306 Química Orgánica
dc.subject.unesco2209.10 Láseres
dc.titleRational molecular design enhancing the photonic performance of red-emitting perylene bisimide dyesen
dc.typejournal article
dc.volume.number19
dspace.entity.typePublication
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relation.isAuthorOfPublication0486160c-3df6-4270-bf91-3e96cd33d85d
relation.isAuthorOfPublication07f337af-8a30-4929-81db-4e92176e5c87
relation.isAuthorOfPublication.latestForDiscoverybee889c2-938d-48d9-8748-01e3c8bf5614
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