Aviso: para depositar documentos, por favor, inicia sesión e identifícate con tu cuenta de correo institucional de la UCM con el botón MI CUENTA UCM. No emplees la opción AUTENTICACIÓN CON CONTRASEÑA
 

A Novel Photoconductive PVK/SiO_2 Interpenetrated Network Prepared by the Sol−Gel Process

dc.contributor.authorRamos Zapata, Gonzalo
dc.contributor.authorBelenguer Dávila, Tomás
dc.contributor.authorMonte Muñoz de la Peña, Francisco de
dc.contributor.authorLevy, David
dc.contributor.authorBernabeu Martínez, Eusebio
dc.date.accessioned2023-06-20T10:46:50Z
dc.date.available2023-06-20T10:46:50Z
dc.date.issued2003-01-09
dc.description© 2003 American Chemical Society. The authors are grateful to the CICYT for the research grant MAT 2001-5073-E. Gonzalo Ramos is also grateful to INTA for a Rafael Calvo Rodés fellowship.
dc.description.abstractIn this work, we describe the preparation of a novel photoconductive sol−gel material based on an organic/inorganic interpenetrating network (IPN). The composition of the sol−gel photoconductive material mimics the well-known polymeric one based on poly(N-vinylcarbazole) (PVK) as the charge-transporting matrix and 2,4,7-trinitro-9-fluorenone (TNF) as the sensitizer. The resulting photoconductive material (PVK/SiO_2 IPN) shows a photosensitivity of 10^-11 cm/(Ω W) in range to that reported for some analogue polymeric compounds and the highest ever reported for hybrid sol−gel materials.
dc.description.departmentDepto. de Óptica
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipComisión Interministerial de Ciencia y Tecnología (CICYT), España
dc.description.sponsorshipInstituto Nacional de Técnica Aerospacial (INTA), España
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/26762
dc.identifier.doi10.1021/jp026759+
dc.identifier.issn1520-6106
dc.identifier.officialurlhttp://dx.doi.org/10.1021/jp026759+
dc.identifier.relatedurlhttp://pubs.acs.org
dc.identifier.urihttps://hdl.handle.net/20.500.14352/51208
dc.issue.number1
dc.journal.titleJournal Of Physical Chemistry B
dc.language.isoeng
dc.page.final112
dc.page.initial110
dc.publisherAmer Chemical Soc
dc.relation.projectIDMAT 2001-5073-E
dc.relation.projectID"Rafael Calvo Rodés"
dc.rights.accessRightsopen access
dc.subject.cdu535
dc.subject.keywordPhotorefractive Polymer
dc.subject.keywordPhotogeneration
dc.subject.keywordComposites
dc.subject.keywordTransport
dc.subject.ucmÓptica (Física)
dc.subject.unesco2209.19 Óptica Física
dc.titleA Novel Photoconductive PVK/SiO_2 Interpenetrated Network Prepared by the Sol−Gel Process
dc.typejournal article
dc.volume.number107
dcterms.references(1) Zhang, Y.; Burzynski, R.; Ghosal, S.; Casstevens, M. K. AdV. Mater. 1996, 8, 111. (2) Penwell, R. C.; Ganguly, B. N.; Smith, T. W. J. Polym. Sci. Macromol. ReV. 1978, 13, 63. (3) (a) Urbach, J. C.; Meier, R. W. Appl. Opt. 1966, 5, 666. (b) Hariharan, P. Optical Holography. Principles, Techniques and Applications; Cambridge University Press: Cambridge, 1984. (4) Carreño, F.; Martínez-Antón, J. C.; Bernabéu, E. Thin Solid Films 1995, 263, 206. (5) (a) Winiarz, J. G.; Zhang, L.; Lal, M.; Friend, C. S.; Prasad, P. N. Chem. Phys. 1999, 245, 417. (b) Winiarz, J. G.; Zhang, L.; Lal, M.; Friend, C. S.; Prasad, P. N. J. Am. Chem. Soc. 1999, 121, 5287. (6) Moerner, W. E.; Silence, S. M. Chem. ReV. 1994, 94, 127. (7) Bolink, H. J.; Krasnikov, V. V.; Malliaras, G. G.; Hadziioannou, G. J. Phys. Chem. 1996, 100, 16356. (8) Malliaras, G. G.; Krasnikov, V. V.; Bolink, H. J.; Hadziioannou, G. Appl. Phys. Lett. 1995, 67, 455. (9) Gubler, U.; He, M.; Wright, D.; Roh, Y.; Twieg, R.; Moerner, W. E. AdV. Mater. 2002, 14, 313. (10) West, K. S.; West, D. P.; Rahn, M. D.; Shakos, J. D.; Wade, F. A.; Khand, K.; King, T. A. J. Appl. Phys. 1998, 84, 5893. (11) Jung, J.; Glowacki, I.; Ulanski, J. J. Chem. Phys. 1999, 110, 7000. (12) Okamoto, K.; Nomura, T.; Park, S.; Ogino, K.; Sato, H. Chem. Mater. 1999, 11, 3279. (13) Winiarz, J. G.; Zhang, L.; Park, J.; Prasad, P. N. J. Phys. Chem. B 2002, 106, 967. (14) Da¨ubler, T. K.; Bittner, R.; Meerholz, K.; Cimrová, V.; Neher, D. Phys. ReV. B 2000, 61, 13515. (15) Cottin, P.; Lessard, R. A.; Knystautas, EÄ . J.; Roorda, S. Nucl. Instrum. Methods Phys. Res. B 1999, 151, 97. (16) Bittner, R.; Meerholz, K.; Stepanov, S. Appl. Phys. Lett. 1999, 74, 3723. (17) Safoula, G.; Bernede, J. C.; Touihri, S.; Alimi, K. Eur. Polym. J. 1998, 34, 1871. (18) West, K. S.; Rahn, D. P.; Shakos, J. D.; Wade, F. A.; Khand, K.; King, T. A. J. Appl. Phys. 1998, 84, 5893. (19) Mercher, E.; Bräuchle, C.; Hörhold, H. H.; Hummelen, J. C.; Meerholz, K. Phys. Chem. Chem. Phys. 1999, 1, 1749. (20) Darracq, B.; Chaput, F.; Lahlil, K.; Boilot, J. P.; Levy, Y.; Alain, V.; Ventelon, L.; Blanchard-Desce, M. Opt. Mater. 1998, 9, 265. (21) Wang, Y.; Wang, X.; Li, J.; Mo, Z.; Zhao, X.; Jing, X.; Wang, F. Adv. Mater. 2001, 13, 1582. (22) Cheben, P.; del Monte, F.; Worsfold, D. J.; Carlsson, D. J.; Grover, C. P.; Mackenzie, J. D. Nature 2000, 408, 64. (23) Wang, S.; Yang, S.; Yang, C.; Li, Z.; Wang, J.; Ge, W. J. Phys. Chem. B 2000, 104, 11853. (24) Chen, Y.; Cai, R. F.; Xiao, L. X.; Huang, Z. E.; Pan, D. J. Mater. Sci. 1998, 33, 4633. (25) Sandalphon, Kippelen, B.; Peyghambarian, N.; Lyon, S. R.; Padias, A. B.; Hall, H. K., Jr. Opt. Lett. 1994, 19, 68. (26) Saleh, B. E. A.; Teich, M. C. Fundamental of Photonics; Goodman, J. W., Ed.; John Wiley & Sons: New York, 1991; Chapter 18. (27) Herlocker, J. A.; Fuentes-Herna´ndez, C.; Ferrio, K. B.; Hendrickx, E.; Blanche, P. A.; Peyghambarian, N.; Kippelen, B.; Zhang, Y.; Wang, J. F.; Marder, S. R. Appl. Phys. Lett. 2000, 77, 2292. (28) Hendrickx, E.; Zhang, Y.; Ferrio, K. B.; Herlocker, J. A.; Anderson, J.; Armstrong, N. R.; Mash, E. A.; Persoons, A. P.; Peyghambarian, N.; Kippelen, B. J. Mater. Chem. 1999, 9, 2251.
dspace.entity.typePublication
relation.isAuthorOfPublication5a8cfd67-3d9a-48ad-8819-2e3b9e7da48d
relation.isAuthorOfPublication.latestForDiscovery5a8cfd67-3d9a-48ad-8819-2e3b9e7da48d

Download

Original bundle

Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
Bernabeu,E65.pdf
Size:
41.13 KB
Format:
Adobe Portable Document Format

Collections