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FormylBODIPYs by PCC-Promoted Selective Oxidation of α-MethylBODIPYs. Synthetic Versatility and Applications

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dc.contributor.authorRamos Torres, Ágata
dc.contributor.authorAvellanal Zaballa, Edurne
dc.contributor.authorPrieto Castañeda, Alejandro
dc.contributor.authorGarcía Garrido, Fernando
dc.contributor.authorBañuelos Prieto, Jorge
dc.contributor.authorRodríguez Agarrabeitia, Antonia
dc.contributor.authorOrtiz García, María Josefa
dc.date.accessioned2023-06-17T13:27:37Z
dc.date.available2023-06-17T13:27:37Z
dc.date.issued2019-06
dc.descriptionReceived: 26/04/2019; Published: 10/06/2019
dc.description.abstractAn efficient synthesis of formylBODIPYs has been established based on an oxidation with PCC of 3-methylBODIPYs. It has been demonstrated that this reagent can oxidize methyl groups at such position of the BODIPY core, regardless of its substitution pattern. Moreover, through this procedure it is possible to synthesize 8-aryl-3,5-diformylBODIPYs, which are otherwise difficult to obtain. These precursors have been functionalized to develop fluorescent sensors of amino acids or photosensitizers for singlet oxygen generation.
dc.description.departmentSección Deptal. de Química Orgánica (Óptica y Optometría)
dc.description.facultyFac. de Óptica y Optometría
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Economía y Competitividad (MINECO)
dc.description.sponsorshipGobierno Vasco
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/56926
dc.identifier.doi10.1021/acs.orglett.9b01465.
dc.identifier.issn1523-7060
dc.identifier.officialurlhttp://pubs.acs.org/doi/abs/10.1021/acs.orglett.9b01465
dc.identifier.relatedurlhttps://pubs.acs.org/doi/10.1021/acs.orglett.9b01465
dc.identifier.urihttps://hdl.handle.net/20.500.14352/13538
dc.journal.titleOrganic Letters
dc.language.isoeng
dc.page.final4566
dc.page.initial4563
dc.publisherACS (American Chemical Society)
dc.relation.projectID(MAT2017-83856-C3-2-P; MAT2017-83856-C3-3-P)
dc.relation.projectIDIT912-16
dc.rights.accessRightsrestricted access
dc.subject.cdu547.1
dc.subject.cdu543.426
dc.subject.keywordFormylBODIPYs
dc.subject.keywordMethylBODIPYs
dc.subject.keywordBODIPYs
dc.subject.keywordFluorescence sensors
dc.subject.keywordPhotosensitizers
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco2306 Química Orgánica
dc.titleFormylBODIPYs by PCC-Promoted Selective Oxidation of α-MethylBODIPYs. Synthetic Versatility and Applications
dc.typejournal article
dc.volume.number21
dspace.entity.typePublication
relation.isAuthorOfPublicationbee889c2-938d-48d9-8748-01e3c8bf5614
relation.isAuthorOfPublication0486160c-3df6-4270-bf91-3e96cd33d85d
relation.isAuthorOfPublication07f337af-8a30-4929-81db-4e92176e5c87
relation.isAuthorOfPublication.latestForDiscoverybee889c2-938d-48d9-8748-01e3c8bf5614

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