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Transition-Metal-Free Direct anti-Carboboration of Alkynes with Boronic Acids To Produce Alkenylheteroarenes

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dc.contributor.authorRoscales García, Silvia
dc.contributor.authorGarcía Csaky, Aurelio
dc.date.accessioned2025-01-27T09:14:10Z
dc.date.available2025-01-27T09:14:10Z
dc.date.issued2015
dc.description.abstractThe transition-metal-free intermolecular direct 1,2-carboboration reaction of heteroarylacetylenes using boronic acids as reagents is achieved by utilizing tartaric acid as promoter. The reaction proceeds with excellent regioselectivity and anti stereoselectivity to afford boroxole frameworks. The resulting compounds are of use for the stereoselective preparation of polysubstituted alkenylheteroarenes.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyInstituto Pluridisciplinar (IP)
dc.description.refereedTRUE
dc.description.sponsorshipUniversidad Complutense de Madrid
dc.description.statuspub
dc.identifier.citationRoscales, Silvia, y Aurelio G. Csákÿ. «Transition-Metal-Free Direct Anti -Carboboration of Alkynes with Boronic Acids To Produce Alkenylheteroarenes». Organic Letters, vol. 17, n.o 6, marzo de 2015, pp. 1605-08. DOI.org (Crossref), https://doi.org/10.1021/acs.orglett.5b00517.
dc.identifier.doi10.1021/acs.orglett.5b00517
dc.identifier.officialurlhttps://doi.org/10.1021/acs.orglett.5b00517
dc.identifier.urihttps://hdl.handle.net/20.500.14352/116175
dc.journal.titleOrganic Letters
dc.language.isoeng
dc.page.final1608
dc.page.initial1605
dc.publisherAmerican Chemical Society
dc.rights.accessRightsrestricted access
dc.subject.cdu547
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco2306 Química Orgánica
dc.titleTransition-Metal-Free Direct anti-Carboboration of Alkynes with Boronic Acids To Produce Alkenylheteroarenes
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number17
dspace.entity.typePublication
relation.isAuthorOfPublicationef4f93d7-a007-4514-9055-f8ba8c41138d
relation.isAuthorOfPublication20fb9911-4424-43a0-ad98-890ff7a6dacd
relation.isAuthorOfPublication.latestForDiscoveryef4f93d7-a007-4514-9055-f8ba8c41138d

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