Solvent-Controlled Switching of Cycloisomerization to Transposition in the Ag/Cu-Promoted Reaction of Terminal α-Allenols
| dc.contributor.author | Toledano Pinedo, Mireia | |
| dc.contributor.author | Anatóliev, Hristo | |
| dc.contributor.author | Martínez Del Campo, Teresa | |
| dc.contributor.author | Almendros, Pedro | |
| dc.date.accessioned | 2023-06-17T09:09:17Z | |
| dc.date.available | 2023-06-17T09:09:17Z | |
| dc.date.issued | 2019-11-14 | |
| dc.description.abstract | We report herein a study on the Ag/Cu-catalyzed reactivity of α-allenols. The focus was the development of new methodologies for cyclization and/or transposition of this moiety. By simple solvent switch, the divergent preparation of dihydrofurans and 3-halo-3-alkenals in a controlled manner has been reached. | |
| dc.description.department | Depto. de Química Orgánica | |
| dc.description.faculty | Fac. de Ciencias Químicas | |
| dc.description.refereed | TRUE | |
| dc.description.sponsorship | Ministerio de Ciencia e Innovación (MICINN)/FEDER | |
| dc.description.status | pub | |
| dc.eprint.id | https://eprints.ucm.es/id/eprint/66785 | |
| dc.identifier.doi | 10.3390/ecsoc-23-06467 | |
| dc.identifier.issn | 2504-3900 | |
| dc.identifier.officialurl | https://doi.org/10.3390/ecsoc-23-06467 | |
| dc.identifier.relatedurl | https://www.mdpi.com/2504-3900/41/1/58 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14352/8288 | |
| dc.issue.number | 1 | |
| dc.journal.title | Proceedings | |
| dc.language.iso | eng | |
| dc.page.initial | 58 | |
| dc.publisher | MDPI | |
| dc.relation.projectID | PGC2018-095025-B-I00 | |
| dc.rights | Atribución 3.0 España | |
| dc.rights.accessRights | open access | |
| dc.rights.uri | https://creativecommons.org/licenses/by/3.0/es/ | |
| dc.subject.keyword | allene | |
| dc.subject.keyword | dihydrofurans and 3-halo-3-alkenals | |
| dc.subject.ucm | Química orgánica (Química) | |
| dc.subject.unesco | 2306 Química Orgánica | |
| dc.title | Solvent-Controlled Switching of Cycloisomerization to Transposition in the Ag/Cu-Promoted Reaction of Terminal α-Allenols | |
| dc.type | journal article | |
| dc.volume.number | 41 | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | cc1cf4f2-577a-41ea-9854-93e787f6e1f6 | |
| relation.isAuthorOfPublication.latestForDiscovery | cc1cf4f2-577a-41ea-9854-93e787f6e1f6 |
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