Sorption and permeation of solutions of chloride salts, water and methanol in a Nafion membrane
| dc.contributor.author | García Villaluenga, Juan Pedro | |
| dc.contributor.author | Barragán García, Vicenta María | |
| dc.contributor.author | Seoane Rodríguez, Benjamín | |
| dc.contributor.author | Ruiz Bauzá, Carlos | |
| dc.date.accessioned | 2023-06-20T10:33:57Z | |
| dc.date.available | 2023-06-20T10:33:57Z | |
| dc.date.issued | 2006-09-15 | |
| dc.description | © 2006 Elsevier Ltd. | |
| dc.description.abstract | The sorption of water-methanol mixtures containing a dissolved chloride salt in a Nafion 117 membrane, and their transport through the membrane under the driving force of a pressure gradient, have been studied. Both type of experiments was performed by using five different salts: lithium chloride, sodium chloride, cesium chloride, magnesium chloride and calcium chloride. It was observed that both the permeation flow through the membrane and the membrane swelling increase significantly with the methanol content of the solutions. These facts are attributed to the increase in wet membrane porosity, which brings about the increase of the mobility of solvents in the membrane, besides the increase of the mobility of the polymer pendant chains. In contrast, the influence of the type of electrolyte on the membrane porosity and permeability is not very important, with the exception of the CsCl solutions, which is probably due to the small hydration ability of the Cs+ ion. | |
| dc.description.department | Depto. de Estructura de la Materia, Física Térmica y Electrónica | |
| dc.description.faculty | Fac. de Ciencias Físicas | |
| dc.description.refereed | TRUE | |
| dc.description.status | pub | |
| dc.eprint.id | https://eprints.ucm.es/id/eprint/20666 | |
| dc.identifier.doi | 10.1016/j.electacta.2006.04.011 | |
| dc.identifier.issn | 0013-4686 | |
| dc.identifier.officialurl | http://dx.doi.org/10.1016/j.electacta.2006.04.011 | |
| dc.identifier.relatedurl | http://pdn.sciencedirect.com/ | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14352/50547 | |
| dc.issue.number | 28 | |
| dc.journal.title | Electrochimica Acta | |
| dc.language.iso | eng | |
| dc.page.final | 6303 | |
| dc.page.initial | 6297 | |
| dc.publisher | Pergamon-Elsevier Science Ltd | |
| dc.rights.accessRights | restricted access | |
| dc.subject.cdu | 536 | |
| dc.subject.keyword | Ion-Exchange Membranes | |
| dc.subject.keyword | Polymer Electrolyte Membranes | |
| dc.subject.keyword | Fuel-Cells | |
| dc.subject.keyword | Ionomer Membranes | |
| dc.subject.keyword | Transport-Properties | |
| dc.subject.keyword | Solvent Transport | |
| dc.subject.keyword | Self-Diffusion | |
| dc.subject.keyword | Mixtures | |
| dc.subject.keyword | Counterions | |
| dc.subject.keyword | Radiotracer. | |
| dc.subject.ucm | Termodinámica | |
| dc.subject.unesco | 2213 Termodinámica | |
| dc.title | Sorption and permeation of solutions of chloride salts, water and methanol in a Nafion membrane | |
| dc.type | journal article | |
| dc.volume.number | 51 | |
| dcterms.references | [1] F. Helfferich, Ion-Exchange, Dover, New York, 1995. [2] M.H.V. Mulder, Basic Principles of Membrane Technology, Kluwer Academic, Amsterdam, 1991. [3] Y. Osada, T. Nakagawa, Membrane Science and Technology, Marcell Dekker, New York, 1992. [4] T.S. Sorensen, Surface Chemistry and Electrochemistry of Membranes, Marcell Dekker, New York, 1999. [5] C.H. Hamann, V. Theile, S. Koter, J. Membr. Sci. 78 (1993) 147. [6] T.J. Chou, A. Tanioka, J. Colloid Interf. Sci. 212 (1999) 576. [7] P.S. Kauranen, E. Skou, J. Appl. Electrochem. 26 (1996) 909. [8] D. Scott, W. Taama, J. Cruickshank, J. Appl. Electrochem. 28 (1998) 289. [9] A.S. Aricò, P. Cretì, P.L. Antonucci, J. Cho, H. Kim, V. Antonucci, Electrochim. Acta 43 (1998) 3719. [10] X. Yuan, Z. Ma, H. Bueb, J.-F. Drillet, J. Hagen, V.M. Schmidt, Electrochim. Acta 50 (2005) 5172. [11] A. Eisenberg, Macromolecules 3 (1970) 147. [12] T.D. Gierke, G.E. Munn, F.C. Wilson, J. Polym. Sci., Polym. Phys. Ed. 19 (1981) 1687. [13] H.L. Yeager, A. Steck, J. Electrochem. Soc. 128 (1981) 1880. [14] M.W. Verbrugge, R.F. Hill, J. Electrochem. Soc. 137 (1990) 886. [15] M.W. Verbrugge, R.F. Hill, J. Electrochem. Soc. 137 (1990) 893. [16] M.W. Verbrugge, R.F. Hill, J. Electrochem. Soc. 137 (1990) 1131. [17] K.D. Kreuer, J. Membr. Sci. 185 (2001) 29. [18] J.P.G. Villaluenga, B. Seoane, V.M. Barragán, C. Ruiz-Bauzá, J. Colloid. Interf. Sci. 268 (2003) 476. [19] A. Lehmani, P. Turq, M. Perie, J. Perie, J.P. Simonin, J. Electroanal. Chem. 428 (1997) 81. [20] T.A. Zawodzinski, L.O. Sillerud, S. Gottesfeld, J. Phys. Chem. 95 (1991) 6040. [21] K.K. Pushpa, D. Nandan, R.M. Iyer, J.Chem.Soc., Faraday Trans. I 84 (1988) 2047. [22] T. Xue, R.B. Longwell, K. Osseo-Asare, J. Membr. Sci. 58 (1991) 175. [23] T. Okada, H. Satou, M. Okuno, M. Yuasa, J. Phys. Chem. B 106 (2002) 1267. [24] I. Cabasso, Z. Liu, T. Makenzie, J. Membr. Sci. 28 (1986) 109. [25] G. Suresh, Y.M. Scindia, A.K. Pandey, A. Goswami, J. Membr. Sci. 250 (2005) 39. [26] A. Goswami, A. Acharya, A.K. Pandey, J. Phys. Chem. B 105 (2001) 9196. [27] K. Schug, A. Dadgar, J. Phys. Chem. 68 (1964) 106. [28] D. Rivin, C.E. Kendrick, P.W. Gibson, N.S. Schneider, Polymer 42 (2001) 623. [29] E. Skou, P. Kauranen, J. Hentschel, Solid State Ionics 97 (1997) 333. [30] P. Dimitrova, K.A. Friedrich, B.Vogt, U. Stimmimg, J. Electrochem. Chem. 532 (2002) 75. [31] Y. Miura, H. Yoshida, Thermochim. Acta 163 (1990) 161. [32] M. Eikerling, A.A. Kornyshev, U. Stimming, J. Phys. Chem. B 101 (1997) 10807. [33] M. Eikerling, Yu.I. Kharkats, A.A. Kornyshev, Yu.M. Volfkovich, J. Electrochem. Soc. 145 (1998) 2684. [34] K. Ramya, K.S. Dhathathreyan, J. Electroanal. Chem. 542 (2003) 109. [35] D.R. Lide, CRC Handbook of Chemistry and Physics, 81st ed., CRC Press, Boca Raton, 2000. [36] J. Kiepe, A.K. Araujo Rodrigues, S. Horstmann, J. Gmehling, Ind. Eng. Chem. Res. 42 (2003) 2022. [37] D. Nandan, H. Mohan, R.M. Iyer, J. Membr. Sci. 71 (1992) 69. [38] G. Gebel, Polymer 41 (2000) 5829. [39] F. Meier, G. Eigenberger, Electrochim. Acta 49 (2004) 1731. [40] P. Costamagna, Chem. Eng. Sci. 56 (2001) 323. [41] P. Wang, A. Anderko, R.D. Young, Fluid Phase Equilibr. 226 (2004) 71. [42] S. Hietala, S.L. Maunu, F. Sundholm, J. Polym. Sci. Polym. Phys. Ed. 38 (2000) 3277. [43] E. Skou, P. Kauranen, J. Hentschel, Solid State Ionics 97 (1997) 333. [44] C.A. Edmondson, P.E. Stallworth, M.C.Wintersgill, J.J. Fontanella,Y. Dai, S.G. Greenbaum, Electrochim. Acta 43 (1998) 1295. [45] S.S. Sandhu, R.O. Crowther, J.P. Fellner, Electrochim. Acta 20 (2005) 3985. | |
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