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GeO_2 Nanowires Doped with Optically Active Ions

dc.contributor.authorHidalgo Alcalde, Pedro
dc.contributor.authorLiberti, Emanuela
dc.contributor.authorRodriguez lazcano, Yamilet
dc.contributor.authorMéndez Martín, María Bianchi
dc.contributor.authorPiqueras De Noriega, Francisco Javier
dc.date.accessioned2023-06-20T03:37:47Z
dc.date.available2023-06-20T03:37:47Z
dc.date.issued2009-10-01
dc.description© 2009 American Chemical Society. This work has been supported by MEC (Project MAT 2006-01259). The authors are grateful to Dr. Luca Gregoratti at the Sincrotron Trieste for useful advises on XPS measurements.
dc.description.abstractGeO_2 nanowires doped with Eu, Er, or Mn, as well as codoped with each of these ions and Sri, have been grown by a catalyst-free vapor-solid process. The incorporation of Sri has been found, in all cases, to favor the formation of straight wires, which make them more appropriate for waveguiding purposes. Cathodoluminescence (CL.) in the scanning electron microscope (SEM) has been used to investigate the complex light emission from the nanowires. Rare earth ion emission lines and defect related bands have been observed in Eu- and Er-doped nanowires. Optical coupling and waveguiding behavior of Er-doped GeO_2 nanowires have been demonstrated for green laser light and for Er excited luminescence in the wires. In Mn-doped GeO_2 nanowires a band centered at 1.75 eV had been detected. X-ray photoemission measurements show the presence of GeO oxide in the surface of the GeO_2 wires, which influences their native defect structure.
dc.description.departmentDepto. de Física de Materiales
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipMEC
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/24263
dc.identifier.doi10.1021/jp905587c
dc.identifier.issn1932-7447
dc.identifier.officialurlhttp://link.springer.com/article/10.1007%2Fs11051-011-0370-7?LI=true
dc.identifier.relatedurlhttp://link.springer.com/
dc.identifier.urihttps://hdl.handle.net/20.500.14352/44091
dc.issue.number5
dc.journal.titleJournal of Physical Chemistry C
dc.language.isoeng
dc.page.final17205
dc.page.initial17200
dc.publisherAmer Chemical Soc
dc.relation.projectIDMAT 2006-01259
dc.rights.accessRightsopen access
dc.subject.cdu538.9
dc.subject.keywordWave-Guides
dc.subject.keywordPhotoluminescence
dc.subject.keywordGermanium
dc.subject.keywordEr
dc.subject.keywordNanocrystals
dc.subject.keywordNanofibers
dc.subject.keywordSilicon
dc.subject.keywordOrigin
dc.subject.keywordBand
dc.subject.keywordSiO_2
dc.subject.ucmFísica de materiales
dc.titleGeO_2 Nanowires Doped with Optically Active Ions
dc.typejournal article
dc.volume.number13
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