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How to make C-N bonds using boronic acids and their derivatives without transition metals

dc.contributor.authorGarcía Csaky, Aurelio
dc.contributor.authorRoscales García, Silvia
dc.date.accessioned2025-01-09T14:48:18Z
dc.date.available2025-01-09T14:48:18Z
dc.date.issued2020-07
dc.descriptionKey learning points (1) Formation of tetrahedral boronates induces a nucleophilic activation of the carbon backbone of boronic acids and their derivatives (boronic acids, boronate esters, or potassium organotrifluoroborates). (2) N–B coordination of a variety of N-LG reagents (LG = Leaving Group) followed by 1,2-C(B–N)-shift triggers C–N bond formation in the absence of transitionmetals. (3) Deoxygenation of nitro and nitroso groups turns them into useful nitrogen electrophiles for amine formation. (4) Acylboron compounds react with N-LG reagents (LG = leaving group) through their carbonyl group to form hemiaminals that evolve to amides.
dc.description.abstractThis tutorial review describes recent developments in carbon–nitrogen bond-forming reactions (amination, amidation, nitration and nitrosation) that involve the use of boronic acids and some of their derivatives as carbon-nucleophiles in the absence of transition-metals. Issues pertaining to reagents and mechanisms are discussed.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyInstituto Pluridisciplinar (IP)
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia, Innovacio´n y Universidades
dc.description.statuspub
dc.identifier.citationChem. Soc. Rev., 2020,49, 5159-5177
dc.identifier.doi10.1039/c9cs00735k
dc.identifier.officialurlhttps://pubs.rsc.org/en/content/articlelanding/2020/cs/c9cs00735k
dc.identifier.urihttps://hdl.handle.net/20.500.14352/113549
dc.journal.titleChemical Society Reviews
dc.language.isoeng
dc.page.final5177
dc.page.initial5159
dc.publisherRoyal Society of Chemistry
dc.relation.projectIDRTI2018-096520-B-I00
dc.rights.accessRightsrestricted access
dc.subject.ucmCiencias
dc.subject.unesco23 Química
dc.titleHow to make C-N bonds using boronic acids and their derivatives without transition metals
dc.title.alternativeCómo hacer enlaces C-N usando ácidos borónicos y sus derivados sin usar metales de transición
dc.typejournal article
dc.type.hasVersionAM
dc.volume.number49
dspace.entity.typePublication
relation.isAuthorOfPublication20fb9911-4424-43a0-ad98-890ff7a6dacd
relation.isAuthorOfPublicationef4f93d7-a007-4514-9055-f8ba8c41138d
relation.isAuthorOfPublication.latestForDiscovery20fb9911-4424-43a0-ad98-890ff7a6dacd

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