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Luminescence and Raman study of α-Bi_2O_3 ceramics

dc.contributor.authorPiqueras De Noriega, Francisco Javier
dc.contributor.authorVila Santos, María
dc.contributor.authorDíaz-Guerra Viejo, Carlos
dc.date.accessioned2023-06-20T03:36:27Z
dc.date.available2023-06-20T03:36:27Z
dc.date.issued2012-03-15
dc.description©2012 Elsevier B.V. This work has been supported by MICINN through projects MAT2009-07882 and CSD2009-0013 and by BSCH-UCM (Project GR35-10A-910146).
dc.description.abstractCathodoluminescence in the scanning electron microscope and photoluminescence in a confocal microscope have been used to investigate the luminescence properties of the stable monoclinic α-phase of Bi_2O_3. Powders of this oxide have been sintered at temperatures of 500 °C and 750 °C in air or in nitrogen atmospheres. Spectra of the starting powder and of the samples treated at 500 °C show luminescence bands at 1.50 eV and 1.95 eV as well as a band at 2.1 eV, more prominent in nitrogen treated samples. Sintering at 750 °C leads to quenching of the 1.50 eV infrared emission and the formation of a broad band with emission above 3 eV. The evolution of Raman bands with the sintering treatments has also been investigated.
dc.description.departmentDepto. de Física de Materiales
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipMICINN (Ministerio de Ciencia e Innovación, España)
dc.description.sponsorshipBSCH-UCM
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/23632
dc.identifier.doi10.1016/j.matchemphys.2012.01.088
dc.identifier.issn0254-0584
dc.identifier.officialurlhttp://dx.doi.org/10.1016/j.matchemphys.2012.01.088
dc.identifier.relatedurlhttp://www.sciencedirect.com
dc.identifier.urihttps://hdl.handle.net/20.500.14352/44026
dc.issue.number1
dc.journal.titleMaterials Chemistry and Physics
dc.language.isoeng
dc.page.final564
dc.page.initial559
dc.publisherElsevier Science SA
dc.relation.projectIDMAT2009-07882
dc.relation.projectIDCSD2009-0013
dc.rights.accessRightsrestricted access
dc.subject.cdu538.9
dc.subject.keywordTrioxide Thin-Films
dc.subject.keywordBismuth Oxide
dc.subject.keywordOptical-Properties
dc.subject.keywordSpectra
dc.subject.keywordPhase
dc.subject.keywordBi_2O_3
dc.subject.keywordBismuthsesquioxide
dc.subject.keywordEvaporation
dc.subject.ucmFísica de materiales
dc.titleLuminescence and Raman study of α-Bi_2O_3 ceramics
dc.typejournal article
dc.volume.number133
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