Copper-mediated divergent reactivity of allene-tethered carbamates under radical conditions

Simple item page
dc.contributor.authorToledano-Pinedo, M.
dc.contributor.authorQuirós, M.
dc.contributor.authorPadrón, I.
dc.contributor.authorHalka, D.
dc.contributor.authorGeorgiou, X.
dc.contributor.authorMartínez Del Campo, Teresa
dc.contributor.authorLuna Costales, Amparo
dc.contributor.authorAlmendros, P.
dc.date.accessioned2025-07-30T08:14:41Z
dc.date.available2025-07-30T08:14:41Z
dc.date.issued2025-06-12
dc.description.abstractBy judicious selection of reaction conditions, the controllable copper-promoted bromoheterocyclization or the sulfonylation/dimerization of allenyl carbamates to access 5- bromo-6-methylene-1,3 oxazinan-2-ones or bis(γ-amino vinyl sulfones) has been implemented. The described method, which is easy to scale up and exhibits good functional group tolerance, displays exquisite selectivity control for the preparation of two structurally different compounds starting from the same precursors under free radical conditions.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.statuspub
dc.identifier.doi10.1021/acs.orglett.5c01990
dc.identifier.officialurlhttps://doi.org/10.1021/acs.orglett.5c01990
dc.identifier.urihttps://hdl.handle.net/20.500.14352/122893
dc.journal.titleOrg. Lett.
dc.language.isoeng
dc.page.final6829
dc.page.initial6823
dc.publisherACS
dc.rights.accessRightsopen access
dc.subject.cdu547
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco2306 Química Orgánica
dc.titleCopper-mediated divergent reactivity of allene-tethered carbamates under radical conditions
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number27
dspace.entity.typePublication
relation.isAuthorOfPublicationcc1cf4f2-577a-41ea-9854-93e787f6e1f6
relation.isAuthorOfPublication14581fe9-97b8-4d33-920f-23f4778c49f7
relation.isAuthorOfPublication.latestForDiscoverycc1cf4f2-577a-41ea-9854-93e787f6e1f6

Download

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
2025 Org. Lett. Reactivity of Allene-Tethered Carbamates.pdf
Size:
1.87 MB
Format:
Adobe Portable Document Format
Download Download

Collections

Artículos