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Spark plasma versus conventional sintering in the electrical properties of Nasicon-type materials

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dc.contributor.authorPérez Estébanez, M.
dc.contributor.authorIsasi Marín, Josefa
dc.contributor.authorRivera Calzada, Alberto Carlos
dc.contributor.authorLeón Yebra, Carlos
dc.contributor.authorNygren, M.
dc.date.accessioned2023-06-18T06:49:27Z
dc.date.available2023-06-18T06:49:27Z
dc.date.issued2015-12-05
dc.description© 2016 Elsevier B.V. This research has been financed by the “Ministerio de Ciencia e Innovación” (MICINN, Spain) and by the “Fundación Neurociencias y Envejecimiento” (Spain) through grants MAT2010-18432 and 4153592, 4143942 respectively as well as by the MAT2013-40722-R project.
dc.description.abstractLi_(1+x)M_(x)Ti_(2−x)(PO_(4))_(3) powders with x = 0 and 0.3 and M = Al, Cr and Fe have been sintered by conventional sintering (CS) and Spark Plasma Sintering (SPS), and the electrical properties have been compared. The use of SPS allows preparing samples with higher density at lower temperature and shorter time than the CS, avoiding segregation of secondary phases and with reduced crystallite size. The introduction of aluminum, chromium and iron in the LiTi_(2)(PO_(4))_(3) (LTP) clearly enhances ionic conductivity even if the samples have similar densities. Despite the different level of density reached with CS and SPS, the activation energies of dc and grain boundary contributions are very similar and the differences in ionic conductivity are determined by pre-exponential factors. The samples produced by SPS showed a well-defined grain boundary meaning a more homogenous electrical contact.
dc.description.departmentDepto. de Estructura de la Materia, Física Térmica y Electrónica
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia e Innovación (MICINN, Spain)
dc.description.sponsorshipFundación Neurociencias y Envejecimiento (Spain)
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/35284
dc.identifier.doi10.1016/j.jallcom.2015.08.126
dc.identifier.issn0925-8388
dc.identifier.officialurlhttp://dx.doi.org/10.1016/j.jallcom.2015.08.126
dc.identifier.relatedurlhttp://www.sciencedirect.com/
dc.identifier.urihttps://hdl.handle.net/20.500.14352/24313
dc.journal.titleJournal of alloys and compounds
dc.language.isoeng
dc.page.final642
dc.page.initial636
dc.publisherElsevier Science SA
dc.relation.projectIDMAT2010-18432
dc.relation.projectID4153592
dc.relation.projectID4143942
dc.relation.projectIDMAT2013-40722-R
dc.rights.accessRightsopen access
dc.subject.cdu537
dc.subject.keywordConducting solid-electrolyte
dc.subject.keywordLithium secondary battery
dc.subject.keywordLi-ion conductors
dc.subject.keywordGlass-ceramics
dc.subject.keywordSuperionic conductivity
dc.subject.keywordLiTi2(PO4)(3)
dc.subject.keywordLi2O-Al2O3-TiO2-P2O5
dc.subject.keywordDependence
dc.subject.keywordImpedance
dc.subject.keywordChromium.
dc.subject.ucmElectricidad
dc.subject.ucmElectrónica (Física)
dc.subject.unesco2202.03 Electricidad
dc.titleSpark plasma versus conventional sintering in the electrical properties of Nasicon-type materials
dc.typejournal article
dc.volume.number651
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