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Swelling and electro-osmotic properties of cation-exchange membranes with different structures in methanol-water media

dc.contributor.authorBarragán García, Vicenta María
dc.contributor.authorGarcía Villaluenga, Juan Pedro
dc.contributor.authorGodino Gómez, María Paz
dc.contributor.authorIzquierdo Gil, María Amparo
dc.contributor.authorRuiz Bauzá, Carlos
dc.contributor.authorSeoane Rodríguez, Benjamín
dc.date.accessioned2023-06-20T10:33:55Z
dc.date.available2023-06-20T10:33:55Z
dc.date.issued2008-12-01
dc.description© 2008 Elsevier B.V, The authors gratefully acknowledge Prof. C. Larchet and Prof. V. Nikonenko for donating MK40 membrane samples. Financial support from Comunidad de Madrid and Universidad Complutense de Madrid under project CCG06(UCM/MAT(1037 is also gratefully acknowledged.
dc.description.abstractElectro-osmosis experiments through three cation-exchange membranes with different morphology and similar electric properties have been performed using methanol-water solutions under different experimental conditions. The influence on the electro-osmotic transport of the percentage of methanol on solvent with two different electrolytes, NaCl and LiCl, has been studied. The experimental results show that the presence of methanol in the solutions affects strongly the electro-osmotic flow, and this influence is different depending on the membrane morphology. Correlations among electro-osmotic permeability, swelling behavior, and cell resistance are studied for these membrane systems at different percentages of methanol in solvent.
dc.description.departmentDepto. de Estructura de la Materia, Física Térmica y Electrónica
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipComunidad de Madrid
dc.description.sponsorshipUniversidad Complutense de Madrid
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/20633
dc.identifier.doi10.1016/j.jpowsour.2008.07.043
dc.identifier.issn0378-7753
dc.identifier.officialurlhttp://dx.doi.org/10.1016/j.jpowsour.2008.07.043
dc.identifier.relatedurlhttp://pdn.sciencedirect.com/
dc.identifier.urihttps://hdl.handle.net/20.500.14352/50544
dc.issue.number2
dc.journal.titleJournal of Power Sources
dc.language.isoeng
dc.page.final827
dc.page.initial822
dc.publisherElsevier Science BV
dc.relation.projectIDCCG06(UCM/MAT(1037
dc.rights.accessRightsrestricted access
dc.subject.cdu536
dc.subject.keywordFuel-Cells
dc.subject.keywordIon
dc.subject.keywordTransport
dc.subject.keywordElctroosmosis
dc.subject.keywordPermeability
dc.subject.keywordCoefficients
dc.subject.keywordElectrolyte
dc.subject.keywordDiffusion
dc.subject.keywordCrossover.
dc.subject.ucmTermodinámica
dc.subject.unesco2213 Termodinámica
dc.titleSwelling and electro-osmotic properties of cation-exchange membranes with different structures in methanol-water media
dc.typejournal article
dc.volume.number185
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