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From photosensitizers to light harvesters adapting the molecular structure in all-BODIPY assemblies

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Abstract

Herein we detail a protocol to design dyads and triads based solely on BODIPY dyes as halogen-free singlet oxygen photosensitizers or energy transfer molecular cassettes. The conducted photonic characterization reveals the key role of the BODIPY–BODIPY linkage to finely modulate the balance between the triplet state population and fluorescence decay.

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Submitted 05 Mar 2021 / Accepted 19 Apr 2021 / First published 19 Apr 2021. This journal is © the Owner Societies 2021. Electronic supplementary information (ESI) available: Synthetic, photophysical, computational and laser details, as well as characterization data including NMR spectra of the new compounds, as well as Table S1 and Fig. S1–S3. See DOI: 10.1039/d1cp00991e

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