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Effect of an ac perturbation on the electroosmotic behavior of a cation-exchange membrane. Influence of the cation nature

dc.contributor.authorBarragán García, Vicenta María
dc.contributor.authorRuiz Bauzá, Carlos
dc.date.accessioned2023-06-20T18:43:14Z
dc.date.available2023-06-20T18:43:14Z
dc.date.issued2001-08-01
dc.description© 2001 by Academic Press. Financial support from the University Complutense of Madrid under Project PR49/98-7756 is gratefully acknowledged.
dc.description.abstractThe effect of an ac sinusoidal perturbation of known amplitude and frequency superimposed on the usual dc applied electric voltage difference on the electroosmotic flow through a typical cation-exchange membrane has been studied using different monovalent electrolytes. As a general trend, the presence of the ac perturbation increases the value of the electroosmotic flow with respect to the value in the absence of ac perturbation. A dispersion of the electroosmotic permeability on the frequency of the applied ac signal has been found for the three studied electrolytes, observing that the electroosmotic permeability reaches maximum values for some characteristic values of the frequency. This behavior may be related to the different relaxation processes in heterogeneous mediums.
dc.description.departmentDepto. de Estructura de la Materia, Física Térmica y Electrónica
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipUniversidad Complutense de Madrid
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/21071
dc.identifier.doi10.1006/jcis.2001.7610
dc.identifier.issn0021-9797
dc.identifier.officialurlhttp://dx.doi.org/10.1006/jcis.2001.7610
dc.identifier.relatedurlhttp://pdn.sciencedirect.com/
dc.identifier.urihttps://hdl.handle.net/20.500.14352/58424
dc.issue.number1
dc.journal.titleJournal of Colloid and Interface Science
dc.language.isoeng
dc.page.final189
dc.page.initial182
dc.publisherAcademic Press Inc Elsevier Science
dc.relation.projectIDPR49/98-7756
dc.rights.accessRightsrestricted access
dc.subject.cdu536
dc.subject.keywordFrequency Dielectric-Dispersion
dc.subject.keywordCellulose-Acetate Membranes
dc.subject.keywordImpedance Spectra
dc.subject.keywordWater
dc.subject.keywordPermeability
dc.subject.keywordPermeation.
dc.subject.ucmTermodinámica
dc.subject.unesco2213 Termodinámica
dc.titleEffect of an ac perturbation on the electroosmotic behavior of a cation-exchange membrane. Influence of the cation nature
dc.typejournal article
dc.volume.number240
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