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BCl3‑Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions

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dc.contributor.authorRay Leiva, César
dc.contributor.authorSchad, Christopher
dc.contributor.authorMoreno Jiménez, Florencio
dc.contributor.authorMaroto, Beatriz Lora
dc.contributor.authorBañuelos Prieto, Jorge
dc.contributor.authorArbeloa, Teresa
dc.contributor.authorGarcía Moreno, Inmaculada
dc.contributor.authorVillafuerte, Cassie
dc.contributor.authorMuller, Gilles
dc.contributor.authorMoya Cerero, Santiago de la
dc.date.accessioned2023-06-17T09:21:59Z
dc.date.available2023-06-17T09:21:59Z
dc.date.issued2020-03-06
dc.description.abstractA general and straightforward method for the synthesis of COO-BODIPYs from F-BODIPYs and carboxylic acids is established. The method is based on the use of boron trichloride to activate the involved substitution of fluorine, which leads to high yields through rapid reactions under soft conditions. This mild method opens the way to unprecedented laser dyes with outstanding efficiencies and photostabilities, which are difficult to obtain by the current methods.
dc.description.departmentSección Deptal. de Química Orgánica (Óptica y Optometría)
dc.description.facultyFac. de Óptica y Optometría
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia e Innovación (España)
dc.description.sponsorshipGobierno Vasco
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/69714
dc.identifier.citationRay C, Schad C, Moreno F, Maroto BL, Bañuelos J, Arbeloa T, García-Moreno I, Villafuerte C, Muller G, De La Moya S. BCl3 -Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions. J Org Chem 2020; 85: 4594–4601. [DOI: 10.1021/acs.joc.9b03059]
dc.identifier.doi10.1021/acs.joc.9b03059
dc.identifier.issn0022-3263 (Print) 1520-6904(Online)
dc.identifier.officialurlhttps://dx.doi.org/10.1021/acs.joc.9b03059
dc.identifier.relatedurlhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC7272132/
dc.identifier.relatedurlhttps://www.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pubmed&retmode=ref&cmd=prlinks&id=32138513
dc.identifier.urihttps://hdl.handle.net/20.500.14352/8663
dc.issue.number7
dc.journal.titleJournal of organic chemistry
dc.language.isoeng
dc.page.final4601
dc.page.initial4594
dc.publisherACS
dc.relation.projectID(MAT2017-83856-C3-1-P MAT2017-83856-C3-2-P and MAT2017-83856-C3-3-P)
dc.relation.projectIDIT(912-16)
dc.relation.projectID(1 SC3 GM089589-08)
dc.rights.accessRightsrestricted access
dc.subject.cdu550.43
dc.subject.cdu544.53
dc.subject.cdu543.544
dc.subject.cdu547-32
dc.subject.keywordCOO-BODIPY
dc.subject.keywordLaser dyes
dc.subject.keywordPhotostabilities
dc.subject.keywordChromatography
dc.subject.keywordDyes and pigments
dc.subject.keywordLasers
dc.subject.keywordOrganic acids
dc.subject.keywordSilica
dc.subject.ucmMateriales
dc.subject.ucmQuímica orgánica (Química)
dc.subject.ucmLáseres
dc.subject.unesco3312 Tecnología de Materiales
dc.subject.unesco2306 Química Orgánica
dc.subject.unesco2209.10 Láseres
dc.titleBCl3‑Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions
dc.typejournal article
dc.volume.number85
dspace.entity.typePublication
relation.isAuthorOfPublication09111c59-3829-4b92-a9d2-ee099b545e9e
relation.isAuthorOfPublication7940c6e8-25c3-4083-b533-0c34e155dfa8
relation.isAuthorOfPublication.latestForDiscovery09111c59-3829-4b92-a9d2-ee099b545e9e

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