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An N-annulated, rylene-based twistacene as scaffold for long supramolecular polymers

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dc.contributor.authorMartínez, Manuel Ángel
dc.contributor.authorGreciano Raiskila, Elisa E.
dc.contributor.authorLópez Gandul, Lucía
dc.contributor.authorSánchez Martín, Luis
dc.date.accessioned2023-06-22T12:27:40Z
dc.date.available2023-06-22T12:27:40Z
dc.date.issued2022-10-27
dc.descriptionCRUE-CSIC (Acuerdos Transformativos 2022)
dc.description.abstractThe multistep synthesis of the N-annulated rylenecarbodiimide 1 is reported. The large p-surface and the operation of a fourfold array of H-bonding interactions between the trialkoxybenzamide units yield highly stable supramolecular polymers, the stability of which has been quantified by applying the denaturation model. The operation of these non-covalent interactions affords long 1D-supramolecular polymers that have been visualized by atomic force microscopy (AFM).
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia e Innovación (MICINN)
dc.description.sponsorshipComunidad de Madrid
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/75262
dc.identifier.doi10.1002/cnma.202200417
dc.identifier.issn2199-692X
dc.identifier.officialurlhttps://doi.org/10.1002/cnma.202200417
dc.identifier.urihttps://hdl.handle.net/20.500.14352/72554
dc.journal.titleChemNanoMat
dc.language.isoeng
dc.publisherWiley
dc.relation.projectIDPID2020-113512GB-I00; RED2018-102331-T
dc.relation.projectIDS2018/NMT-4389
dc.rightsAtribución-NoComercial 3.0 España
dc.rights.accessRightsopen access
dc.rights.urihttps://creativecommons.org/licenses/by-nc/3.0/es/
dc.subject.keywordAFM
dc.subject.keywordcooperativity
dc.subject.keywordrylenes
dc.subject.keywordsupramolecular polymers
dc.subject.keywordthermodynamics
dc.subject.ucmQuímica
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco23 Química
dc.subject.unesco2306 Química Orgánica
dc.titleAn N-annulated, rylene-based twistacene as scaffold for long supramolecular polymers
dc.typejournal article
dspace.entity.typePublication
relation.isAuthorOfPublication8601c77b-23fe-40a1-87fe-c4d276227d02
relation.isAuthorOfPublication.latestForDiscovery8601c77b-23fe-40a1-87fe-c4d276227d02

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