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Investigation of Fickian diffusion in the ternary mixture of 1,2,3,4-tetrahydronaphthalene, isobutylbenzene, and dodecane

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dc.contributor.authorMialdun, A.
dc.contributor.authorSechenyh, V.
dc.contributor.authorLegros, J. C.
dc.contributor.authorOrtiz De Zárate Leira, José María
dc.contributor.authorShevtsova, V.
dc.date.accessioned2023-06-19T13:26:16Z
dc.date.available2023-06-19T13:26:16Z
dc.date.issued2013-09-14
dc.description© 2013 AIP Publishing LLC. This work is supported by the PRODEX programme of the Belgian Federal Science Policy Office, ESA. The authors would like to thank referee for useful discussion of the fitting algorithms.
dc.description.abstractWe present a comprehensive analysis of experimental results obtained for Fickian diffusion in the benchmark ternary liquid mixture of 1,2,3,4-tetrahydronaphthalene, isobutylbenzene, and dodecane (nC(12)) with equal mass fractions. Isothermal diffusion coefficients have been measured by two independent experimental methods: by Taylor dispersion technique, and by a counter flow cell fitted with an optical interferometry device. The experimental diffusion matrices have been critically analyzed regarding the Onsager reciprocal relations, for which we introduce a matrix asymmetry index S-2 that is independent of the frame of reference and the component order.
dc.description.departmentDepto. de Estructura de la Materia, Física Térmica y Electrónica
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipPRODEX programme of the Belgian Federal Science Policy Office, ESA
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/27267
dc.identifier.doi10.1063/1.4820357
dc.identifier.issn0021-9606
dc.identifier.officialurlhttp://dx.doi.org/10.1063/1.4820357
dc.identifier.relatedurlhttp://scitation.aip.org/
dc.identifier.urihttps://hdl.handle.net/20.500.14352/33689
dc.issue.number10
dc.journal.titleJournal of Chemical Physics
dc.language.isoeng
dc.publisherAmerican Institute of Physics
dc.rights.accessRightsopen access
dc.subject.cdu536
dc.subject.keywordTaylor dispersion technique
dc.subject.keywordOptical-properties
dc.subject.keywordLight-scattering
dc.subject.keywordLiquid-mixtures
dc.subject.keywordCoefficients
dc.subject.keywordBinary
dc.subject.keywordInterferometry
dc.subject.keywordCyclohexane
dc.subject.keywordMethanol
dc.subject.keywordToluene
dc.subject.ucmTermodinámica
dc.subject.unesco2213 Termodinámica
dc.titleInvestigation of Fickian diffusion in the ternary mixture of 1,2,3,4-tetrahydronaphthalene, isobutylbenzene, and dodecane
dc.typejournal article
dc.volume.number139
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