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Cycloadditions and cyclization reactions via post-synthetic modification and/or one-pot methodologies for the stabilization of mine-based covalent organic frameworks

dc.contributor.authorGala Sánchez, Elena
dc.contributor.authorRamos, M. Mar
dc.contributor.authorSegura Castedo, José Luis
dc.date.accessioned2024-05-16T07:50:43Z
dc.date.available2024-05-16T07:50:43Z
dc.date.issued2023-06-25
dc.description2023 Descuentos MDPI
dc.description.abstractInterest in covalent organic frameworks as high-value materials has grown steadily since their development in the 2000s. However, the great advantage that allows us to obtain these crystalline materials—the reversibility of the bonds that form the network—supposes a drawback in terms of thermal and chemical stability. Among the different strategies employed for the stabilization of imine-based Covalent Organic Frameworks (COFs), cycloaddition and other related cyclization reactions are especially significant to obtain highly stable networks with extended π-delocalization and new functionalities, expanding even further the potential application of these materials. Therefore, this entry gathered the most recent research strategies for obtaining stable COFs by means of cyclization reactions, including the Povarov reaction and intramolecular oxidative cyclization reactions as well as some other recent innovative approaches.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.fundingtypeDescuento UCM
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia e Innovación (España)
dc.description.sponsorshipUniversidad Complutense de Madrid
dc.description.statuspub
dc.identifier.citationGala, E.; Ramos, M.M.; Segura, J.L. Cycloadditions and Cyclization Reactions via Post-Synthetic Modification and/or One-Pot Methodologies for the Stabilization of Imine-Based Covalent Organic Frameworks. Encyclopedia 2023, 3, 795-807. https://doi.org/10.3390/encyclopedia3030057
dc.identifier.doi10.3390/encyclopedia3030057
dc.identifier.essn2673-8392
dc.identifier.officialurlhttps://doi.org/10.3390/encyclopedia3030057
dc.identifier.urihttps://hdl.handle.net/20.500.14352/104060
dc.issue.number3
dc.journal.titleEncyclopedia
dc.language.isoeng
dc.page.final807
dc.page.initial795
dc.publisherMDPI
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-106268GB-C33/ES/DISEÑO DE MATERIALES 2D PARA APLICACIONES EN ENERGIA: REDES ORGANICAS COVALENTES/
dc.relation.projectIDinfo:eu-repo/grantAgreement///TED2021- 129886B-C43/ES///
dc.relation.projectIDinfo:eu-repo/grantAgreement/Universidad Complutense de Madrid//INV.GR.00.1819.10759/ES///
dc.rightsAttribution 4.0 Internationalen
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subject.cdu547
dc.subject.keywordCovalent organic frameworks
dc.subject.keywordPost-synthetic modification
dc.subject.keywordOne-pot synthesis
dc.subject.keywordStabilization
dc.subject.keywordImine-based-COFs
dc.subject.keywordCycloaddition reaction
dc.subject.keywordPovarov reaction
dc.subject.keywordAza-Diels–Alder
dc.subject.keywordOxidative cyclization
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco2306 Química Orgánica
dc.titleCycloadditions and cyclization reactions via post-synthetic modification and/or one-pot methodologies for the stabilization of mine-based covalent organic frameworks
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number3
dspace.entity.typePublication
relation.isAuthorOfPublication5ade8ed4-46bd-442c-93ff-f67fd9714a3d
relation.isAuthorOfPublication78c95fd7-2774-4a6c-b42a-212d583cba93
relation.isAuthorOfPublication.latestForDiscovery5ade8ed4-46bd-442c-93ff-f67fd9714a3d

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