Cycloadditions and cyclization reactions via post-synthetic modification and/or one-pot methodologies for the stabilization of mine-based covalent organic frameworks
dc.contributor.author | Gala Sánchez, Elena | |
dc.contributor.author | Ramos, M. Mar | |
dc.contributor.author | Segura Castedo, José Luis | |
dc.date.accessioned | 2024-05-16T07:50:43Z | |
dc.date.available | 2024-05-16T07:50:43Z | |
dc.date.issued | 2023-06-25 | |
dc.description | 2023 Descuentos MDPI | |
dc.description.abstract | Interest in covalent organic frameworks as high-value materials has grown steadily since their development in the 2000s. However, the great advantage that allows us to obtain these crystalline materials—the reversibility of the bonds that form the network—supposes a drawback in terms of thermal and chemical stability. Among the different strategies employed for the stabilization of imine-based Covalent Organic Frameworks (COFs), cycloaddition and other related cyclization reactions are especially significant to obtain highly stable networks with extended π-delocalization and new functionalities, expanding even further the potential application of these materials. Therefore, this entry gathered the most recent research strategies for obtaining stable COFs by means of cyclization reactions, including the Povarov reaction and intramolecular oxidative cyclization reactions as well as some other recent innovative approaches. | |
dc.description.department | Depto. de Química Orgánica | |
dc.description.faculty | Fac. de Ciencias Químicas | |
dc.description.fundingtype | Descuento UCM | |
dc.description.refereed | TRUE | |
dc.description.sponsorship | Ministerio de Ciencia e Innovación (España) | |
dc.description.sponsorship | Universidad Complutense de Madrid | |
dc.description.status | pub | |
dc.identifier.citation | Gala, E.; Ramos, M.M.; Segura, J.L. Cycloadditions and Cyclization Reactions via Post-Synthetic Modification and/or One-Pot Methodologies for the Stabilization of Imine-Based Covalent Organic Frameworks. Encyclopedia 2023, 3, 795-807. https://doi.org/10.3390/encyclopedia3030057 | |
dc.identifier.doi | 10.3390/encyclopedia3030057 | |
dc.identifier.essn | 2673-8392 | |
dc.identifier.officialurl | https://doi.org/10.3390/encyclopedia3030057 | |
dc.identifier.uri | https://hdl.handle.net/20.500.14352/104060 | |
dc.issue.number | 3 | |
dc.journal.title | Encyclopedia | |
dc.language.iso | eng | |
dc.page.final | 807 | |
dc.page.initial | 795 | |
dc.publisher | MDPI | |
dc.relation.projectID | info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-106268GB-C33/ES/DISEÑO DE MATERIALES 2D PARA APLICACIONES EN ENERGIA: REDES ORGANICAS COVALENTES/ | |
dc.relation.projectID | info:eu-repo/grantAgreement///TED2021- 129886B-C43/ES/// | |
dc.relation.projectID | info:eu-repo/grantAgreement/Universidad Complutense de Madrid//INV.GR.00.1819.10759/ES/// | |
dc.rights | Attribution 4.0 International | en |
dc.rights.accessRights | open access | |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
dc.subject.cdu | 547 | |
dc.subject.keyword | Covalent organic frameworks | |
dc.subject.keyword | Post-synthetic modification | |
dc.subject.keyword | One-pot synthesis | |
dc.subject.keyword | Stabilization | |
dc.subject.keyword | Imine-based-COFs | |
dc.subject.keyword | Cycloaddition reaction | |
dc.subject.keyword | Povarov reaction | |
dc.subject.keyword | Aza-Diels–Alder | |
dc.subject.keyword | Oxidative cyclization | |
dc.subject.ucm | Química orgánica (Química) | |
dc.subject.unesco | 2306 Química Orgánica | |
dc.title | Cycloadditions and cyclization reactions via post-synthetic modification and/or one-pot methodologies for the stabilization of mine-based covalent organic frameworks | |
dc.type | journal article | |
dc.type.hasVersion | VoR | |
dc.volume.number | 3 | |
dspace.entity.type | Publication | |
relation.isAuthorOfPublication | 5ade8ed4-46bd-442c-93ff-f67fd9714a3d | |
relation.isAuthorOfPublication | 78c95fd7-2774-4a6c-b42a-212d583cba93 | |
relation.isAuthorOfPublication.latestForDiscovery | 5ade8ed4-46bd-442c-93ff-f67fd9714a3d |
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