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Anhydrous lithium acetate polymorphs and its hydrates: three-dimensional coordination polymers

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dc.contributor.authorMartínez Casado, F.J.
dc.contributor.authorRamos Riesco, M.
dc.contributor.authorRedondo, M.I.
dc.contributor.authorChoquesillo-Lazarte, D
dc.contributor.authorLópez De Andrés, María Sol
dc.contributor.authorRodríguez Cheda, J.A.
dc.date.accessioned2023-10-05T08:32:17Z
dc.date.available2023-10-05T08:32:17Z
dc.date.issued2011
dc.descriptionS Supporting Information. Crystallographic information files. This material is available free of charge via the Internet at http://pubs.acs.org.The structure reported in this paper may be obtained from the Cambridge Crystallographic Data Center, on quoting the depository numbers CCDC-770300 and CCDC-770301, for 1A at 100 and 298 K, respectively, CCDC-739978 and CCDC-739979, for 2 at 100 and 298 K, respectively, and CCDC-802905, CCDC-739980, CCDC-739976 and CCDC- 739977, for 1B, 3, 4 and 5, respectively (at 100 K).
dc.description.abstractLithium acetate is a very common salt with many and varied uses. Nevertheless, only two compounds were known apparently, the anhydrous salt and lithium acetate dihydrate, but only the latter was really characterized. In this paper, two polymorphs of anhydrous lithium acetate and three novel hydrates (with lithium acetate/H2O ratios 4:1, 7:3, and 1:1) are reported for the first time, besides the well-known lithium acetate dihydrate. The five new compounds are three-dimensional (3D) coordination polymers, different from the one-dimensional (1D) structure of lithium acetate dihydrate. The structures and the relative stability of the two anhydrous lithium acetate polymorphs are also compared. The compounds were studied by single crystal X-ray diffraction (SCXRD), powder X-ray diffraction (PXRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and infrared spectroscopy (FTIR).
dc.description.departmentDepto. de Mineralogía y Petrología
dc.description.facultyFac. de Ciencias Geológicas
dc.description.refereedTRUE
dc.description.statuspub
dc.identifier.citationCryst. Growth Des. 2011, 11, 4, 1021–1032 Publication Date:March 7, 2011 https://doi.org/10.1021/cg1010133
dc.identifier.doi10.1021/cg1010133
dc.identifier.essn1528-7505
dc.identifier.issn1528-7483
dc.identifier.officialurlhttps://pubs.acs.org/doi/10.1021/cg1010133
dc.identifier.urihttps://hdl.handle.net/20.500.14352/88147
dc.issue.number4
dc.journal.titleCrystal growth & design
dc.language.isoeng
dc.page.final1032
dc.page.initial1021
dc.publisherAmerican Chemical society
dc.relation.projectIDCTQ2008-06328/BQU
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.cdu548
dc.subject.keywordLithium acetate
dc.subject.keywordPolimers
dc.subject.keywordDiffraction X-ray
dc.subject.keywordCrystallography
dc.subject.ucmCristalografía (Geología)
dc.subject.unesco2211.04 Cristalografía
dc.titleAnhydrous lithium acetate polymorphs and its hydrates: three-dimensional coordination polymers
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number11
dspace.entity.typePublication
relation.isAuthorOfPublicatione8889f99-6c40-4a0d-a11b-d305a8a9ecea
relation.isAuthorOfPublication.latestForDiscoverye8889f99-6c40-4a0d-a11b-d305a8a9ecea

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