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Physical properties of high pressure reactively sputtered hafnium oxide

dc.contributor.authorMartil De La Plaza, Ignacio
dc.contributor.authorGonzález Díaz, Germán
dc.contributor.authorPrado Millán, Álvaro Del
dc.contributor.authorSan Andrés Serrano, Enrique
dc.date.accessioned2023-06-20T10:43:56Z
dc.date.available2023-06-20T10:43:56Z
dc.date.issued2008-08-08
dc.descriptionIberian Vacuum Meeting (5.2005.Guimaraes,Portugal). © 2008 Elsevier Ltd. All rights reserved. The authors acknowledge C.A.I de Implantación Iónica (U.C.M.), C.A.I de Espectroscopía y Espectrometría and C.A.I. de Microscopía y Citometría for technical support. This work was made possible thanks to a FPU grant of the Spanish M.E.C. This work was also supported by the Spanish M.C.Y.T., under the contract TEC 2004-1237/MIC.
dc.description.abstractHafnium oxide films were deposited on silicon by High Pressure Reactive Sputtering (HPRS) at pressures between 0.8 and 1.6 mbar. Growth, composition and morphology were investigated using Transmission Electron Microscopy (TEM), Heavy Ion Elastic Recoil Detection Analysis (HI-ERDA), Fourier Transform infrared spectroscopy (FTIR) and X-Ray Diffraction (XRD). The growth rate was found to decrease exponentially with deposition pressure. The films showed a monoclinic polycrystalline structure, with higher grain size for intermediate pressures. All the films were slightly oxygen rich with respect to stoichiometric HfO2, which is attributed to the oxygen plasma. Additionally, it was observed the formation of an interfacial silicon oxide layer, with a minimum thickness for deposition pressures around 1.2 mbar. These results are explained by the oxidation action of the oxygen plasma and the diffusion of oxygen through the grain boundaries of the HfO2 film.
dc.description.departmentDepto. de Estructura de la Materia, Física Térmica y Electrónica
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipFPU grant of the Spanish M.E.C.
dc.description.sponsorshipSpanish M.C.Y.T.
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/25959
dc.identifier.doi10.1016/j.vacuum.2008.03.083
dc.identifier.issn0042-207X
dc.identifier.officialurlhttp://dx.doi.org/10.1016/j.vacuum.2008.03.083
dc.identifier.relatedurlhttp://www.sciencedirect.com
dc.identifier.urihttps://hdl.handle.net/20.500.14352/51099
dc.issue.number12
dc.journal.titleVacuum
dc.language.isoeng
dc.page.final1394
dc.page.initial1391
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.projectIDTEC 2004-1237/MIC
dc.rights.accessRightsopen access
dc.subject.cdu537
dc.subject.keywordElectron-Cyclotron-Resonance
dc.subject.keywordThin-Films
dc.subject.keywordOptical-Properties
dc.subject.keywordSioxnyhz Films
dc.subject.keywordHFO2
dc.subject.keywordERDA
dc.subject.keywordSi.
dc.subject.ucmElectricidad
dc.subject.ucmElectrónica (Física)
dc.subject.unesco2202.03 Electricidad
dc.titlePhysical properties of high pressure reactively sputtered hafnium oxide
dc.typejournal article
dc.volume.number82
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