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A novel modification of the Ritter reaction: stereoselective synthesis of bridgehead-fused Δ2-norbornanethiazolines from thiocamphor and thiofenchone

dc.contributor.authorGarcía Martínez, Antonio
dc.contributor.authorTeso Vilar, Enrique
dc.contributor.authorMoreno Jiménez, Florencio
dc.contributor.authorÁlvarez García, Ana María
dc.date.accessioned2023-06-20T12:55:58Z
dc.date.available2023-06-20T12:55:58Z
dc.date.issued2006-11-17
dc.descriptionReceived 18 September 2006, Accepted 2 November 2006, Available online 1 December 2006.
dc.description.abstractAn easy two-step route for the stereoselective synthesis of novel bridgehead-fused norbornanethiazolines from readily available natural camphor and fenchone is described. The key step of the synthetic route is the highly stereoselective trapping of 1-(trifluoromethylsulfonylthio)-2-norbornyl cations by nitriles followed by intramolecular cyclization, which constitutes a new modification of the Ritter reaction
dc.description.departmentSección Deptal. de Química Orgánica (Óptica y Optometría)
dc.description.facultyFac. de Óptica y Optometría
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia e Innovación (MICINN)
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/71168
dc.identifier.doidoi.org/10.1016/j.tetasy.2006.11.003
dc.identifier.issn0957-4166
dc.identifier.officialurlhttps://doi.org/10.1016/j.tetasy.2006.11.003
dc.identifier.urihttps://hdl.handle.net/20.500.14352/52834
dc.issue.number21
dc.journal.titleTetrahedron: Asymmetry
dc.language.isoeng
dc.page.final2975
dc.page.initial2970
dc.publisherElsevier
dc.relation.projectIDTQ(2004-07244-CO2-02/BQU)
dc.rights.accessRightsrestricted access
dc.subject.cdu547.1
dc.subject.keywordRitter reaction
dc.subject.keywordnorbornanethiazolines
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco2306 Química Orgánica
dc.titleA novel modification of the Ritter reaction: stereoselective synthesis of bridgehead-fused Δ2-norbornanethiazolines from thiocamphor and thiofenchone
dc.typejournal article
dc.volume.number17
dspace.entity.typePublication
relation.isAuthorOfPublication09111c59-3829-4b92-a9d2-ee099b545e9e
relation.isAuthorOfPublication.latestForDiscovery09111c59-3829-4b92-a9d2-ee099b545e9e

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