A novel modification of the Ritter reaction: stereoselective synthesis of bridgehead-fused Δ2-norbornanethiazolines from thiocamphor and thiofenchone
dc.contributor.author | García Martínez, Antonio | |
dc.contributor.author | Teso Vilar, Enrique | |
dc.contributor.author | Moreno Jiménez, Florencio | |
dc.contributor.author | Álvarez García, Ana María | |
dc.date.accessioned | 2023-06-20T12:55:58Z | |
dc.date.available | 2023-06-20T12:55:58Z | |
dc.date.issued | 2006-11-17 | |
dc.description | Received 18 September 2006, Accepted 2 November 2006, Available online 1 December 2006. | |
dc.description.abstract | An easy two-step route for the stereoselective synthesis of novel bridgehead-fused norbornanethiazolines from readily available natural camphor and fenchone is described. The key step of the synthetic route is the highly stereoselective trapping of 1-(trifluoromethylsulfonylthio)-2-norbornyl cations by nitriles followed by intramolecular cyclization, which constitutes a new modification of the Ritter reaction | |
dc.description.department | Sección Deptal. de Química Orgánica (Óptica y Optometría) | |
dc.description.faculty | Fac. de Óptica y Optometría | |
dc.description.refereed | TRUE | |
dc.description.sponsorship | Ministerio de Ciencia e Innovación (MICINN) | |
dc.description.status | pub | |
dc.eprint.id | https://eprints.ucm.es/id/eprint/71168 | |
dc.identifier.doi | doi.org/10.1016/j.tetasy.2006.11.003 | |
dc.identifier.issn | 0957-4166 | |
dc.identifier.officialurl | https://doi.org/10.1016/j.tetasy.2006.11.003 | |
dc.identifier.uri | https://hdl.handle.net/20.500.14352/52834 | |
dc.issue.number | 21 | |
dc.journal.title | Tetrahedron: Asymmetry | |
dc.language.iso | eng | |
dc.page.final | 2975 | |
dc.page.initial | 2970 | |
dc.publisher | Elsevier | |
dc.relation.projectID | TQ(2004-07244-CO2-02/BQU) | |
dc.rights.accessRights | restricted access | |
dc.subject.cdu | 547.1 | |
dc.subject.keyword | Ritter reaction | |
dc.subject.keyword | norbornanethiazolines | |
dc.subject.ucm | Química orgánica (Química) | |
dc.subject.unesco | 2306 Química Orgánica | |
dc.title | A novel modification of the Ritter reaction: stereoselective synthesis of bridgehead-fused Δ2-norbornanethiazolines from thiocamphor and thiofenchone | |
dc.type | journal article | |
dc.volume.number | 17 | |
dspace.entity.type | Publication | |
relation.isAuthorOfPublication | 09111c59-3829-4b92-a9d2-ee099b545e9e | |
relation.isAuthorOfPublication.latestForDiscovery | 09111c59-3829-4b92-a9d2-ee099b545e9e |
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