A novel and simple procedure for the enantiospecific synthesis of bridgehead norbornane thioethers and thiocyanates

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dc.contributor.authorGarcı́a Martı́nez, Antonio
dc.contributor.authorTeso Vilar, Enrique
dc.contributor.authorMoreno Jiménez, Florencio
dc.contributor.authorÁlvarez García, Ana María
dc.contributor.authorPinilla Rodríguez, Patricia
dc.date.accessioned2023-06-20T17:22:42Z
dc.date.available2023-06-20T17:22:42Z
dc.date.issued2002-12-11
dc.description.abstractAn easy three-step route for the enantiospecific synthesis of novel 1-norbornyl thioethers and thiocyanates from readily available natural fenchone and camphor is described. The key step of the synthetic route is the nucleophilic substitution over the sulfenyl sulfur atom of the intermediate thiotriflates by the corresponding C-nucleophiles.
dc.description.departmentSección Deptal. de Química Orgánica (Óptica y Optometría)
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Óptica y Optometría
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia y Tecnología de España (MCYT)
dc.description.sponsorshipUniversidad Nacional de Educación a Distancia (UNED) (España)
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/71182
dc.identifier.doi10.1016/S0957-4166(02)00716-4
dc.identifier.issn0957-4166
dc.identifier.officialurlhttps://doi.org/10.1016/S0957-4166(02)00716-4
dc.identifier.urihttps://hdl.handle.net/20.500.14352/58168
dc.issue.number24
dc.journal.titleTetrahedron: Asymmetry
dc.language.isoeng
dc.page.final2639
dc.page.initial2635
dc.publisherElsevier science Ltd.
dc.relation.projectIDBQU(2001-1347-C02-02)
dc.relation.projectID2001V/PROYT/18
dc.rights.accessRightsrestricted access
dc.subject.cdu542.9
dc.subject.cdu66.091
dc.subject.cdu547.1
dc.subject.ucmPartículas
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco2208 Nucleónica
dc.subject.unesco2306 Química Orgánica
dc.titleA novel and simple procedure for the enantiospecific synthesis of bridgehead norbornane thioethers and thiocyanates
dc.typejournal article
dc.volume.number13
dspace.entity.typePublication
relation.isAuthorOfPublication09111c59-3829-4b92-a9d2-ee099b545e9e
relation.isAuthorOfPublication.latestForDiscovery09111c59-3829-4b92-a9d2-ee099b545e9e

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