Pervaporation of alcohols and methyl tert-butyl ether through a dense poly(2,6-dimethyl-1,4-phenylene oxide) membrane
| dc.contributor.author | García Villaluenga, Juan Pedro | |
| dc.contributor.author | Godino Gómez, María Paz | |
| dc.contributor.author | Khayet Souhaimi, Mohamed | |
| dc.contributor.author | Seoane Rodríguez, Benjamín | |
| dc.contributor.author | Mengual Cabezón, Juan Ignacio | |
| dc.date.accessioned | 2023-06-20T10:41:24Z | |
| dc.date.available | 2023-06-20T10:41:24Z | |
| dc.date.issued | 2004-05-12 | |
| dc.description | © 2004 American Chemical Society. Financial support from the University Complutense of Madrid under Project PR78/02-10993 is gratefully acknowledged. | |
| dc.description.abstract | Pervaporation separation and swelling experiments of methanol/methyl tert-butyl ether mixtures were performed by using a flat-sheet, dense poly(2,6-dimethyl-1,4-phenylene oxide) membrane prepared from a chloroform casting solvent. The effect of the feed composition on the membrane performance was described by the permeability of the components, the separation factor, and the sorption selectivity. The effect of the feed temperature on the separation was also studied, and the Arrhenius activation energy for permeability was determined over the whole range of feed composition. Pervaporation operations offered a maximum methanol selectivity of 5.4 and an overall normalized flux of 110 kg(.)mum/m(2)-h. Pervaporation and sorption experiments were also conducted using ethanol, propanol, butanol, and octanol to study the effect of the size of the alcohol molecule on the transport across the membrane. | |
| dc.description.department | Depto. de Estructura de la Materia, Física Térmica y Electrónica | |
| dc.description.faculty | Fac. de Ciencias Físicas | |
| dc.description.refereed | TRUE | |
| dc.description.sponsorship | University Complutense of Madrid | |
| dc.description.status | pub | |
| dc.eprint.id | https://eprints.ucm.es/id/eprint/24915 | |
| dc.identifier.doi | 10.1021/ie034299g | |
| dc.identifier.issn | 0888-5885 | |
| dc.identifier.officialurl | http://dx.doi.org/10.1021/ie034299g | |
| dc.identifier.relatedurl | http://pubs.acs.org/ | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14352/51001 | |
| dc.issue.number | 10 | |
| dc.journal.title | Industrial and engineering chemistry research | |
| dc.language.iso | eng | |
| dc.page.final | 2555 | |
| dc.page.initial | 2548 | |
| dc.relation.projectID | PR78/02-10993 | |
| dc.rights.accessRights | restricted access | |
| dc.subject.cdu | 536 | |
| dc.subject.keyword | Methanol-Selective Membranes | |
| dc.subject.keyword | Vapor-Liquid-Equilibria | |
| dc.subject.keyword | Composite Membranes | |
| dc.subject.keyword | Cellulose-Acetate | |
| dc.subject.keyword | Pva Membranes | |
| dc.subject.keyword | Ether/Methanol Mixtures | |
| dc.subject.keyword | Ethylene-Glycol | |
| dc.subject.keyword | Mtbe Mixtures | |
| dc.subject.keyword | Separation | |
| dc.subject.keyword | Binary | |
| dc.subject.ucm | Termodinámica | |
| dc.subject.unesco | 2213 Termodinámica | |
| dc.title | Pervaporation of alcohols and methyl tert-butyl ether through a dense poly(2,6-dimethyl-1,4-phenylene oxide) membrane | |
| dc.type | journal article | |
| dc.volume.number | 43 | |
| dcterms.references | (1) Wijmans, J. G.; Baker, R. W. The solution-diffusion model: a review. J. Membr. Sci. 1995, 107, 1. (2) Feng, X.; Huang, R. Y. M. Liquid separation by membrane pervaporation: a review. Ind. Eng. Chem. Res. 1997, 36, 1048. (3) Fleming, H. L.; Slater, C. S. Applications and Economics. In Membrane Handbook; Ho, W. S. W., Winston, W. S., Eds.; Chapman and Hall: New York, 1992; Chapter 10. (4) Wesslein, M.; Heintz, A.; Lichtenthaler, R. N. Pervaporation of liquid mixtures through poly(vinyl alcohol) (PVA) membranes. I. Study of water containing binary system with complete and partial miscibility. J. Membr. Sci. 1990, 51, 169. (5) Jiraratanon, R.; Chanachai, A.; Huang, R. Y. M.; Uttapap, D. Pervaporation dehydration of ethanol-water mixtures with chitosan/hydroxyethylcellulose (CS/HEC) composite membranes: I. Effect of operating conditions. J. Membr. Sci. 2002, 195, 143. (6) Maeda, Y.; Kai, M. Recent progress in pervaporation membranes for water/ethanol separation. In Pervaporation Membrane Separation Processes; Huang, R. Y. M., Ed.; Elsevier: Amsterdam, The Netherlands, 1991; Chapter 9. (7) Karlsson, H. O. E.; Trägårdh, G. Pervaporation of dilute organic-water mixtures. A literature review on modelling studies and applications to aroma compound recovery. J. Membr. Sci. 1993, 76, 121. (8) Böddeker, K. W.; Bengtson, G. Selective pervaporation of organics. In Pervaporation Membrane Separation Processes; Huang, R. Y. M., Ed.; Elsevier: Amsterdam, The Netherlands, 1991; Chapter 10. (9) García Villaluenga, J. P.; Tabe-Mohammadi, A. A review on the separation of benzene/cyclohexane by pervaporation processes. J. Membr. Sci. 2000, 169, 159. (10) Moon, G. Y.; Pal, R.; Huang, R. Y. M. N-Acetylated chitosan membranes for the pervaporation separation of alcohol/toluene mixtures. J. Membr. Sci. 2000, 176, 223. (11) Lipnizki, F.; Hausmanns, S.; Ten, P. K.; Field, R. W.; Laufenberg, G. Organophilic pervaporation: prospects and performance. Chem. Eng. J. 1999, 73, 113. (12) Marx, S.; Gryp, P.; Neomagus, H.; Everson, R.; Kleizer, K. Pervaporation separatiin of methanol/tert-amyl methyl ether mixtures with a commercial membrane. J. Membr. Sci. 2002, 209, 353. (13) Yang, J. S.; Kim, H. J.; Jo, W. H.; Kang, Y. S. Analysis of pervaporation of methanol-MTBE mixtures through cellulose acetate and cellulose triacetate membranes. Polymer 1998, 39, 1381. (14) Doghieri, F.; Nardella, A.; Sarti, G. C.; Valentini, C. Pervaporation of methanol-MTBE mixtures through modified poly(phenylene oxide) membranes. J. Membr. Sci. 1994, 91, 283. (15) Park, H. C.; Ramaker, N. E.; Mulder, M. H. V.; Smolders, C. A. Separation of MTBE-methanol mixtures by pervaporation. Sep. Sci. Technol. 1995, 30, 419. (16) Sano, T.; Hasegawa, M.; Kawakami, Y.; Yanagishita, H. Separation of methanol/methyl-tert-butyl ether mixture by pervaporation using silicalite membrane. J. Membr. Sci. 1995, 107, 193. (17) Chen, W.; Martin, C. R. Highly methanol-selective membranes for the pervaporation separation of methyl tert-butyl ether/methanol mixtures. J. Membr. Sci. 1995, 104, 101. (18) Kita, H.; Inoue, T.; Asamura, H.; Tanaka, K.; Okamoto, K. Chem. Commun. 1997, 45. (19) Ray, S. K.; Sawant, S. B.; Pangarkar, V. G. Development of methanol selective membranes for separation of methanolmethyl tertiary butyl ether mixture by pervaporation. J. Appl. Polym. Sci. 1999, 74, 2645. (20) Nam, S. Y.; Lee, Y. M. Pervaporation separation of methanol/methyl tert-butyl ether through chitosan composite membrane modified with surfactants. J. Membr. Sci. 1999, 157, 63. (21) Yoshikawa, M.; Yoshioka, T.; Fujime, J.; Murakami, A. Pervaporation of MeOH/MTBE through agarose membranes. J. Membr. Sci. 2000, 178, 75. (22) Kim, S.; Lim, G.; Jegal, J.; Lee, K. Pervaporation separation of MTBE (methyl tert-butyl ether) and methanol mixtures through polyion complex composite membranes consisting of sodium alginate/chitosan. J. Membr. Sci. 2000, 174, 1. (23) Cao, S.; Shi, Y.; Chen, G. Influence of acetylation degree of cellulose acetate on pervaporation properties for MeOH/MTBE mixture. J. Membr. Sci. 2000, 165, 89. (24) Rhim, J.; Kim, Y. Pervaporation separation of MTBEmethanol mixtures using cross-linked PVA membranes. J. Appl. Polym. Sci. 2000, 75, 1699. (25) Niang, M.; Luo, G. A triacetate cellulose membrane for the separation of methyl tert-butyl ether/methanol mixtures by pervaporation. Sep. Purif. Technol. 2001, 24, 427. (26) Tabe-Mohammadi, A.; Villaluenga, J. P. G.; Kim, H. J.; Chan, T.; Rauw, V. Effects of polymer solvents on the performance of cellulose acetate membranes in methanol/methyl tertiary butyl ether separation. J. Appl. Polym. Sci. 2001, 82, 2882. (27) Yoshikawa, M.; Yoshioka, T.; Fujime, J.; Murakami, A. Pervaporation of methanol/methyl tert-butyl ether mixtures through agarose/hydroxyethylcellulose blended membranes. J. Appl. Polym. Sci. 2002, 86, 3408. (28) Yoshida, W.; Cohen, Y. Ceramic-supported polymer membranes for pervaporation of binary organic/organic mixtures. J. Membr. Sci. 2003, 213, 145. (29) Schwarz, H.; Apostel, R.; Paul, D. Membranes based on polyelectrolyte-surfactant complexes for methanol separation. J. Membr. Sci. 2001, 194, 91. (30) Huang, R. Y. M.; Moon, G. Y.; Pal, R. Chitosan/anionic surfactant complex membranes for the pervaporation separation of methanol/MTBE and characterization of the polymer/surfactant system. J. Membr. Sci. 2001, 184, 1. (31) Farnand, B. A.; Noh, S. H. Pervaporation as an alternative process for the separation of methanol from C4 hydrocarbons in the production of MTBE and TAME. AIChE Symp. Ser. 1989, 85, 89. (32) Chen, M. S. K.; Markiewicz, G. S.; Venogupal, K. G. Development of membrane pervaporation TRIM process for methanol recovery from CH3OH/MTBE/C4 mixtures. AIChE Symp. Ser. 1989, 85, 82. (33) Cao, S.; Shi, Y.; Chen, G. Pervaporation separation of MeOH/MTBE through CTA membrane. J. Appl. Polym. Sci. 1999, 71, 377. (34) Bangxiao, C.; Li, Y.; Hailin, Y.; Congjie, G. Effect of separating layer in pervaporation composite membrane for MTBE/ MeOH separation. J. Membr. Sci. 2001, 194, 151. (35) Eliceche, A. M.; Daviou, M. C.; Hoch, P. M.; Uribe, I. O. Optimisation of azeotropic distillation columns combined with pervaporation membranes. Comput. Chem. Eng. 2002, 26, 563. (36) Hömmerich, U.; Rautenbach, R. Design and optimization of combined pervaporation/distillation processes for the production of MTBE. J. Membr. Sci. 1998, 146, 53. (37) González González, B.; Ortiz Uribe, I. Mathematical modeling of the pervaporative separation of methanol-methyl tertbutyl ether mixtures. Ind. Eng. Chem. Res. 2001, 40, 1720. (38) Zhou, M.; Persin, M.; Sarrazin, J. Methanol removal from organic mixtures by pervaporation using polypyrrole membranes. J. Membr. Sci. 1996, 117, 303. (39) Chowdhury, G.; Kruczek, B.; Matsuura, T. Polyphenylene Oxide and Modified Polyphenylene Oxide Membranes: Gas, Vapor and Liquid Separation; Kluwer Academic Publishers: Dordrecht, The Netherlands, 2001. (40) Khulbe, K. C.; Matsuura, T.; Lamarche, G.; Kim, H. J. The morphology characterization and performance of dense PPO membranes for gas separation. J. Membr. Sci. 1997, 135, 211. (41) Khayet, M.; Villaluenga, J. P. G.; Godino, M. P.; Mengual, J. I.; Seoane, B.; Khulbe, K. C.; Matsuura, T. Development and application of dense poly(phenylene oxide) membranes for pervaporation of methanol-ethylene glycol mixtures. J. Membr. Sci. 2004, submitted for publication. (42) Villaluenga, J. P. G.; Khayet, M.; Godino, P.; Seoane, B.; Mengual, J. I. Pervaporation of toluene/alcohol mixtures through a coextruded linear low-density polyethylene membrane. Ind. Eng. Chem. Res. 2003, 42, 386. (43) Marin, M.; Kalantzi, K.; Gilbert, H. Pervaporation process: membrane conditioning and experimental mass transfer analysis. J. Membr. Sci. 1992, 74, 105. (44) Rautenbach, R.; Hömmerich, U. Experimental study of dynamic mass-transfer effects in pervaporation. AIChE J. 1998, 44, 1210. (45) Burshe, M. C.; Sawant, S. B.; Joshi, J. B.; Pangarkar, V. G. Sorption and permeation of binary water-alcohol systems through PVA membranes crosslinked with multifunctional crosslinking agents. Sep. Sci. Technol. 1997, 12, 145. (46) Sun, Y.; Chen, Y.; Wu, C.; Lin, A. Pervaporation for the mixture of benzene and cyclohexane through PPOP membranes. AIChE J. 1999, 45, 523. (47) Nguyen, Q. T.; Favre, E.; Ping, Z. H.; Néel, J. Clustering of solvents in membranes and its influence on membrane transport properties. J. Membr. Sci. 1996, 113, 137. (48) Wijmans, J. G. A simple predictive treatment of the permeation process in pervaporation. J. Membr. Sci. 1993, 79, 101. (49) Coto, B.; Wiesenberg, R.; Pando, C.; Rubio, R. G.; Renuncio, J. A. R. Vapor-liquid equilibrium of the methanol-tert-butyl methyl ether (MTBE) system. Ver. Bunsen-Ges. Phys. Chem. 1996, 100, 482. (50) Flory, P. Thermodynamics of high-polymer solutions. J. Chem. Phys. 1942, 10, 51. (51) Huggins, M. Thermodynamic properties of solutions of long-chain compounds. Ann. N.Y. Acad. Sci. 1942, 43, 1. (52) Mulder, M. H. V. Thermodynamic principles of pervaporation. In Pervaporation Membrane Separation Processes; Huang, R. Y. M., Ed.; Elsevier: Amsterdam, The Netherlands, 1991; Chapter 4. (53) Drioli, E.; Zhang, S.; Basile, A. On the coupling effect in pervaporation. J. Membr. Sci. 1993, 81, 43. (54) Fleming, H. L.; Slater, C. S. Pervaporation: theory. In Membrane Handbook; Ho, W. S. W., Winston, W. S., Eds.; Chapman and Hall: New York, 1992; Chapter 8. (55) Ray, S. K.; Sawant, S. B.; Joshi, J. B.; Pangarkar, V. G. Methanol selective membranes for separation of methanolethylene glycol mixtures by pervaporation. J. Membr. Sci. 1999, 154, 1. (56) Feng, X.; Huang, R. Y. M. Estimation of activation energy for permeation in pervaporation process. J. Membr. Sci. 1996, 118, 127. (57) Toghiani, R. K.; Toghiani, H.; Venkateswarlu, G. Vaporliquid equilibria for methyl tert-butyl ether + methanol and tertamyl methyl ether + methanol. Fluid Phase Equilib. 1996, 122, 157. (58) Vetere, A.; Miracca, I.; Cianci, F. Correlation and prediction of the vapor-liquid equilibria of the binary and ternary systems involved in MTBE synthesis. Fluid Phase Equilib. 1993, 90, 189. (59) Segovia, J. J.; Martín,M. C.; Chamorro, C. R.; Villamañán, M. A. Excess thermodynamic properties of binary and ternary mixtures containing methyl 1,1-dimethylethyl ether (MTBE), n-heptane, and methanol at T ) 313.15 K. J. Chem. Thermodyn. 1999, 31, 1231. (60) Reid, R. C.; Prausnitz, J. M.; Poling, B. E. Properties of Gases and Liquids, 4th ed.; McGraw-Hill: New York, 1988. (61) Ghosh, I.; Sanyal, S. K.; Mukherjea, R. N. Pervaporation of methanol-ethylene glycol with cellophane membrane: some mechanistic aspects. Ind. Eng. Chem. Res. 1988, 27, 1895. (62) Jiang, J. S.; Greenberg, D. B.; Fried, J. R. Pervaporation of methanol from a triglyme solution using a nafion membrane: 1. Transport studies. J. Membr. Sci. 1997, 132, 255. (63) Nam, S. Y.; Chun, H. J.; Lee, Y. M. Pervaporation separation of water-2-propanol mixture using carboxymethylated poly(vinyl alcohol) composite membranes. J. Appl. Polym. Sci. 1999, 72, 241. | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | 767d7957-0d58-4121-ab42-43d9165389a9 | |
| relation.isAuthorOfPublication | 8e32e718-0959-4e6c-9e04-891d3d43d640 | |
| relation.isAuthorOfPublication | 89cfc24c-28fa-46fc-9b17-8eafe78b3a89 | |
| relation.isAuthorOfPublication | 2b4858d5-d4ad-4758-866f-222349ee1248 | |
| relation.isAuthorOfPublication.latestForDiscovery | 767d7957-0d58-4121-ab42-43d9165389a9 |
Download
Original bundle
1 - 1 of 1