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Influence of the electron-lattice coupling for Cr^3^+ ions in Nb^5^+ site into congruent co-doped LiNbO_3: Cr^3^+: ZnO crystal

dc.contributor.authorMartínez Matos, Óscar
dc.contributor.authorTorchia, Gustavo Adrián
dc.contributor.authorVaveliuk, Pablo
dc.contributor.authorTocho, Jorge Omar
dc.date.accessioned2023-06-20T10:42:06Z
dc.date.available2023-06-20T10:42:06Z
dc.date.issued2003-08
dc.description© 2003 Elsevier Ltd. G.A. Torchia wishes to acknowledge the CONICET (Argentina) for his fellowship.
dc.description.abstractThis paper shows the important role that plays the electron-lattice coupling to represent correctly the energy levels of Cr^3^+ ions in Nb^5^+ site into congruent LiN_bO_3 crystals doped with 5.3% of ZnO. Racah's parameters: and crystal field intensity were determined and the Tanabe–Sugano's diagram was constructed. The characteristics of the absorption and emission spectra of Cr^3^+ ions in Nb^5^+ site have been explained in terms of the Configurational Co-ordinate model in the harmonic approximation. Huang–Rhys parameter, S=3.5 and the breathing phonon energy, are also reported in this work. Different values of breathing phonon for Cr^3^+ in Nb^5^+ site than in Li+ site could explain the higher luminescent quantum efficiency of Cr^3^+ ions located in Nb^5^+ site in LiN_bO_3 crystals.
dc.description.departmentDepto. de Óptica
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipConsejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Argentina
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/25261
dc.identifier.doi10.1016/S0038-1098(03)00508-8
dc.identifier.issn0038-1098
dc.identifier.officialurlhttp://dx.doi.org/10.1016/S0038-1098(03)00508-8
dc.identifier.relatedurlhttp://www.sciencedirect.com/
dc.identifier.urihttps://hdl.handle.net/20.500.14352/51029
dc.issue.number8
dc.journal.titleSolid State Communications
dc.language.isoeng
dc.page.final539
dc.page.initial535
dc.publisherPergamon-Elsevier Science LTD
dc.rights.accessRightsopen access
dc.subject.cdu535
dc.subject.keywordMGO
dc.subject.keywordSpectroscopy
dc.subject.keywordLuminescence
dc.subject.keywordCenters
dc.subject.ucmÓptica (Física)
dc.subject.unesco2209.19 Óptica Física
dc.titleInfluence of the electron-lattice coupling for Cr^3^+ ions in Nb^5^+ site into congruent co-doped LiNbO_3: Cr^3^+: ZnO crystal
dc.typejournal article
dc.volume.number127
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