A facile synthesis of blue luminescent [7]helicenocarbazoles bBased on golcatalyzed rearrangement‐iodonium migration and Suzuki–Miyaura benzannulation reactions
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2018
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Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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Alcaide B, Almendros P, Aragoncillo C, Busto E, López-Calixto C. G, Liras M, de la Peña V A, García-Sánchez A, Stone H. V. A Facile Synthesis of Blue Luminescent [7]Helicenocarbazoles Based on Gold-Catalyzed Rearrangement-Iodonium Migration and Suzuki-Miyaura Benzannulation Reactions. Chem. Eur. J. 2018, 24, 7620-7625.
Abstract
New azahelicenes having interesting photophysical properties have been prepared in a four‐step sequence. These [7]helicenocarbazoles are efficient blue luminophores, demonstrating the utility of gold catalysis in the preparation of advanced materials.