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Comparative study of the implementation of tin and titanium oxide nanoparticles as electrodes materials in Li-ion batteries

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Abstract

Transition metal oxides potentially present higher specific capacities than the current anodes based on carbon, providing an increasing energy density as compared to commercial Li-ion batteries. However, many parameters could influence the performance of the batteries, which depend on the processing of the electrode materials leading to different surface properties, sizes or crystalline phases. In this work a comparative study of tin and titanium oxide nanoparticles synthesized by different methods, undoped or Li doped, used as single components or in mixed ratio, or alternatively forming a composite with graphene oxide have been tested demonstrating an enhancement in capacity with Li doping and better cyclability for mixed phases and composite anodes.

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©2020 The Author(s) This work was supported by MINECO/FEDER/Minerera.net Co-fund/NILS EEA Grants (Project MAT201565274-R, PCIN-2017-106, RTI2018-097195-B-I00 and Project MAT2016-81720-REDC) and the M-ERA, net project 272806 by the Research Council of Norway. F. del P. thanks NILS-EEA Grants (008-ABEL-CM-2013 Project) for the financial support. M. T. thanks MINECO for the FPI grant (RTI2018-097195-B-I00).

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