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C-Branched chiral (racemic) macrocyclic amino acids: Structure of their Ni(ii), Zn(ii) and Cu(ii) complexes

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dc.contributor.authorPellico, D
dc.contributor.authorGómez Gallego, María Del Mar
dc.contributor.authorEscudero, Rosa
dc.contributor.authorRamírez López, P.
dc.contributor.authorOliván, M.
dc.contributor.authorSierra, M.A.
dc.date.accessioned2025-02-02T09:41:53Z
dc.date.available2025-02-02T09:41:53Z
dc.date.issued2011
dc.description.abstractA new procedure for the synthesis of macrocyclic embedded bis-α-amino acids and their use as cation-ligands is described. These compounds are able to form stable Cu(ii), Zn(ii) and Ni(ii) complexes as long as they have a flexible tether between the two nitrogen atoms. For a given macrocycle, the X-ray diffraction studies revealed diastereomerically pure complexes having different geometries depending on the metal ion.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipComunidad de Madrid
dc.description.sponsorshipMinisterio de Ciencia, Innovación y Universidades
dc.description.statuspub
dc.identifier.citationPellico, D., Gómez-Gallego, M., Escudero, R., Ramírez-López, P., Oliván, M., & Sierra, M. A. (2011). C-Branched chiral (racemic) macrocyclic amino acids: Structure of their Ni(ii), Zn(ii) and Cu(ii) complexes. Dalton Transactions, 40(36), 9145-9153. https://doi.org/10.1039/C1DT10539F
dc.identifier.doi10.1039/C1DT10539F
dc.identifier.officialurlttps://doi.org/10.1039/C1DT10539F
dc.identifier.relatedurlhttps://pubs.rsc.org/en/content/articlelanding/2011/dt/c1dt10539f
dc.identifier.urihttps://hdl.handle.net/20.500.14352/117541
dc.issue.number36
dc.journal.titleDalton Transactions
dc.language.isoeng
dc.page.final9153
dc.page.initial9145
dc.publisherThe Royal Society of Chemistry.
dc.relation.projectIDCTQ-2010-20714-C02- 01/BQU
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//CTQ2008-00810/ES/REACCIONES DE ACTIVACION DE ENLACES C-H Y ACOPLAMIENTO C-C Y C-HETEROATOMO PROMOVIDAS POR COMPLEJOS DE METALES DE TRANSICION/
dc.relation.projectIDP2009/PPQ1634-AVANCAT
dc.rights.accessRightsrestricted access
dc.subject.cdu547
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco23 Química
dc.titleC-Branched chiral (racemic) macrocyclic amino acids: Structure of their Ni(ii), Zn(ii) and Cu(ii) complexes
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number40
dspace.entity.typePublication
relation.isAuthorOfPublication12acd2fe-424d-4b6e-970f-adc9d9536bbe
relation.isAuthorOfPublication.latestForDiscovery12acd2fe-424d-4b6e-970f-adc9d9536bbe

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