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Hierarchy of asymmetry in chiral supramolecular polymers: toward functional, helical supramolecular structures

dc.contributor.authorGreciano Raiskila, Elisa Emilia
dc.contributor.authorValera González, Jorge Santos
dc.contributor.authorGómez Aspe, Rafael
dc.contributor.authorSánchez Martín, Luis
dc.date.accessioned2024-07-11T08:05:00Z
dc.date.available2024-07-11T08:05:00Z
dc.date.issued2019
dc.description.abstractThe formation of helical structures through the supramolecular polymerization of a variety of self-assembling units is reviewed. These scaffolds are usually obtained by efficient transfer or amplification of chirality phenomena, in which the starting self-assembling molecules possess different elements of asymmetry, such as point or axial chirality. Relevant examples of helical supramolecular structures investigated under thermodynamic control are reviewed, and the helical outcome of remarkable examples of chiral entities obtained through kinetic control are also highlighted. Finally, selected examples of flexible macroscopic chirality and catalysis are described to illustrate the applicability of helical aggregates.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipMCIU of Spain
dc.description.statuspub
dc.identifier.citationChem. Eur. J. 2019, 25, 5848 – 5864
dc.identifier.doi10.1002/CHEM.201805577
dc.identifier.urihttps://hdl.handle.net/20.500.14352/105945
dc.journal.titleChemistry A European Journal
dc.language.isoeng
dc.page.final18
dc.page.initial1
dc.publisherWiley-VCH
dc.relation.projectIDCTQ2017-82706-P
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.accessRightsrestricted access
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.cdu547
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco2306 Química Orgánica
dc.titleHierarchy of asymmetry in chiral supramolecular polymers: toward functional, helical supramolecular structures
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number25
dspace.entity.typePublication
relation.isAuthorOfPublication0669eb56-6106-450b-9081-c737eb36c56b
relation.isAuthorOfPublication57cd5674-5efa-4bbd-a583-433eefa87ced
relation.isAuthorOfPublication832f5432-563c-495f-9196-7dce78d24c7c
relation.isAuthorOfPublication8601c77b-23fe-40a1-87fe-c4d276227d02
relation.isAuthorOfPublication.latestForDiscovery832f5432-563c-495f-9196-7dce78d24c7c

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