Structural phase transitions in BaTi0₃ studied via perturbed angular correlations

Abstract

Phase transitions in the ferroelectric perovskite BaTiO₃ were studied for ^111In-implanted polycrystalline samples by measuring the electric field gradients by means of Perturbed Angular Correlation spectroscopy. The phase transitions between the orthorhombic double left right arrow rhombohedral double left right arrow tetragonal double left right arrow cubic lattices were investigated in 2 - 10 K steps, for increasing and decreasing temperatures, in order to determine their hysteresis. The transition parameters are compared with results from measurements of the spontaneous polarization, electric susceptibility and neutron scattering.