Redox-active metallacarborane-decorated octasilsesquioxanes. Electrochemical and thermal properties

Cabrera González, Justo Enrique; Sanchez-Arderiu, Víctor; Viñas,  Clara; Parella, Teodor; Teixidor, Francesc; Nuñez, Rosario

Redox-active metallacarborane-decorated octasilsesquioxanes. Electrochemical and thermal properties

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Official URL

https://doi.org/10.1021/acs.inorgchem.6b02394

Publication date

2016

Authors

Cabrera González, Justo Enrique

Sanchez-Arderiu, Víctor

Viñas, Clara

Parella, Teodor

Teixidor, Francesc

Nuñez, Rosario

Publisher

American Chemical Society

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URI

https://hdl.handle.net/20.500.14352/96353

Citation

Cabrera-González J, Sánchez-Arderiu V, Viñas C, Parella T, Teixidor F, Núñez R. Redox-Active Metallacarborane-Decorated Octasilsesquioxanes. Electrochemical and Thermal Properties. Inorg Chem 2016;55:11630–4. https://doi.org/10.1021/acs.inorgchem.6b02394.

Abstract

Polyanionic and electroactive hybrids based on octasilsesquioxanes bearing metallacarborane units are developed. They show remarkable solubility in organic solvents and outstanding thermal stability. The metallacarboranes act as independent units simultaneously undergoing the reversible redox process.