A Dynamic and Responsive Host in Action: Light‐Controlled Molecular Encapsulation

Simple item page
dc.contributor.authorRyan, Seán
dc.contributor.authorBarrio, Jesús del
dc.contributor.authorSuardíaz Delrío, Reynier
dc.contributor.authorRyan, Daniel
dc.contributor.authorRosta, Edina
dc.contributor.authorScherman, Oren
dc.date.accessioned2024-01-11T10:47:15Z
dc.date.available2024-01-11T10:47:15Z
dc.date.issued2016
dc.description.abstractThe rational design of a flexible molecular box, oAzoBox4+ , incoporating both photochromic and supramolecular recognition motifs is described. We exploit the EZ photoisomerization properties of azobenzenes to alter the shape of the cavity of the macrocycle upon absorption of light. Imidazolium motifs are used as hydrogen-bonding donor components, allowing for sequestration of small molecule guests in acetonitrile. Upon E!Z photoisomerization of oAzoBox4+ the guest is expelled from the macrocyclic cavity
dc.description.departmentDepto. de Química Física
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipNASA
dc.description.sponsorshipRobert Gardiner memorial scholarship
dc.description.sponsorshipCambridge University
dc.description.sponsorshipEngineering & Physical Sciences Research Council (Reino Unido)
dc.description.sponsorshipEuropean Commission
dc.description.sponsorshipWalters-Kundert Foundation
dc.description.statuspub
dc.identifier.citationRyan, Seán T. J., et al. «A Dynamic and Responsive Host in Action: Light‐Controlled Molecular Encapsulation». Angewandte Chemie International Edition, vol. 55, n.o 52, diciembre de 2016, pp. 16096-100. https://doi.org/10.1002/anie.201607693.
dc.identifier.doi10.1002/anie.201607693
dc.identifier.essn1521-3773
dc.identifier.issn1433-7851
dc.identifier.officialurlhttps://doi.org/10.1002/anie.201607693
dc.identifier.urihttps://hdl.handle.net/20.500.14352/92478
dc.issue.number52
dc.journal.titleAngewandte Chemie International Edition
dc.language.isoeng
dc.page.final16100
dc.page.initial16096
dc.publisherWiley
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/273807/EU
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/622711/EU
dc.relation.projectIDEP/G060649/1
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/240629/EU
dc.relation.projectIDEP/L000253/1
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internationalen
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject.cdu544
dc.subject.keywordLight
dc.subject.keywordPhotochemical reactions
dc.subject.keywordSupramolecular chemistry
dc.subject.ucmQuímica
dc.subject.unesco23 Química
dc.titleA Dynamic and Responsive Host in Action: Light‐Controlled Molecular Encapsulation
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number55
dspace.entity.typePublication
relation.isAuthorOfPublication8b0c8e63-584d-4205-a5aa-81107b9bd474
relation.isAuthorOfPublication.latestForDiscovery8b0c8e63-584d-4205-a5aa-81107b9bd474

Download

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
A_dynamic_and_responsive_host.pdf
Size:
1.24 MB
Format:
Adobe Portable Document Format
Download Download

Collections

Artículos