N-(Diazoacetyl)oxazolidin-2-thiones as Sulfur-Donor Reagents: Asymmetric Synthesis of Thiiranes from Aldehydes

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dc.contributor.authorCano Rico, Israel
dc.contributor.authorGómez-Bengoa, Enrique
dc.contributor.authorLanda, Aitor
dc.contributor.authorMaestro, Miguel
dc.contributor.authorMielgo, Antonia
dc.contributor.authorOlaizola, Iurre
dc.contributor.authorOiarbide, Mikel
dc.contributor.authorPalomo, Claudio
dc.date.accessioned2024-01-17T11:35:07Z
dc.date.available2024-01-17T11:35:07Z
dc.date.issued2012
dc.description.abstractWe reported the first Rh-catalyzed reaction of a diazoacetyl compound with aldehydes that affords thiiranes, instead of oxiranes, as known before. This unusual reactivity relied on the use of N-(diazoacetyl)oxazolidin-2-thiones as new chiral sulfur-donor reagents and enabled the direct production of optically active thiiranes with very high stereoselectivity.
dc.description.departmentDepto. de Química Inorgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipEusko Jaurlaritza
dc.description.sponsorshipMinisterio de Ciencia, Innovación y Universidades (España)
dc.description.sponsorshipEuropean Commission
dc.description.statuspub
dc.identifier.citationI. Cano, E. Gómez-Bengoa, A. Landa, M. Maestro, A. Mielgo, I. Olaizola, M. Oiarbide, C. Palomo. N-(Diazoacetyl)oxazolidin-2-thiones as sulfur donor reagents: Asymmetric synthesis of thiiranes from aldehydes. Angew. Chem., Int. Ed. 2012, 51, 10856-10860
dc.identifier.doi10.1002/anie.201204771
dc.identifier.essn1521-3773
dc.identifier.issn1433-7851
dc.identifier.officialurlhttps://doi.org/10.1002/anie.201204771
dc.identifier.urihttps://hdl.handle.net/20.500.14352/93578
dc.issue.number43
dc.language.isoeng
dc.page.final10860
dc.page.initial10856
dc.publisherWiley
dc.rights.accessRightsopen access
dc.subject.cdu546
dc.subject.ucmQuímica inorgánica (Química)
dc.subject.unesco2303 Química Inorgánica
dc.titleN-(Diazoacetyl)oxazolidin-2-thiones as Sulfur-Donor Reagents: Asymmetric Synthesis of Thiiranes from Aldehydes
dc.typejournal article
dc.type.hasVersionAM
dc.volume.number51
dspace.entity.typePublication
relation.isAuthorOfPublicationfb27becc-5580-41b0-b53d-edce93f6cd57
relation.isAuthorOfPublication.latestForDiscoveryfb27becc-5580-41b0-b53d-edce93f6cd57
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