Molecular architectures of cationic [Pd(g3 -C3H5)(pzbp2py)]+ complexes and BF 4 and CF3SO 3 as counteranions (pzbp2py = 2-[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]pyridine)

dc.contributor.authorTorralba Martínez, María Del Carmen
dc.contributor.authorCano Esquivel, María Mercedes
dc.contributor.authorCampo Santillana, José Antonio
dc.contributor.authorHeras Castelló, José Vicente
dc.contributor.authorPinilla Aguilar, Elena
dc.contributor.authorTorres, M.R.
dc.contributor.authorPerles Hernáez, Josefina
dc.contributor.authorRuiz Valero, Caridad
dc.date.accessioned2025-01-15T17:19:07Z
dc.date.available2025-01-15T17:19:07Z
dc.date.issued2006
dc.description.abstractThe crystal structures of two complexes containing the 2-[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]pyridine (pzbp2py) ligand bonded to the [Pd(η3-C3H5)]+ fragment and BF4- and CF3 SO3- as counteranions (1 and 2, respectively) have been solved and their molecular architectures compared. The compounds exhibit a 2D network based on weak interactions in which the counterion plays an important role. The molecular layers in the 2D arrangement show interpenetration between the substituent-chains on the pyrazole rings. These features are also observed in related compounds bearing only one chain on the pyrazole ring.
dc.description.departmentDepto. de Mineralogía y Petrología
dc.description.departmentDepto. de Química Inorgánica
dc.description.facultyFac. de Ciencias Geológicas
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Educación y ciencia (España)
dc.description.sponsorshipComunidad de Madrid
dc.description.statuspub
dc.identifier.citationTorralba, M. C., et al. «Molecular Architectures of Cationic [Pd(Η3-C3H5)(Pzbp2py)]+ Complexes and and as Counteranions (Pzbp2py=2-[3,5-Bis(4-Butoxyphenyl)Pyrazol-1-Yl]Pyridine)». Journal of Organometallic Chemistry, vol. 691, n.o 12, junio de 2006, pp. 2614-22. DOI.org (Crossref), https://doi.org/10.1016/j.jorganchem.2005.12.071
dc.identifier.doi10.1016/j.jorganchem.2005.12.071
dc.identifier.essn1872-8561
dc.identifier.issn0022-328X
dc.identifier.officialurlhttps://doi.org/10.1016/j.jorganchem.2005.12.071
dc.identifier.urihttps://hdl.handle.net/20.500.14352/114525
dc.issue.number12
dc.journal.titleJournal of organometallic chemistry
dc.language.isoeng
dc.page.final2622
dc.page.initial2614
dc.publisherElsevier
dc.relation.projectIDMEC (DGI BQU2003-07343)
dc.relation.projectIDCAM ( GR/MAT/0511/2004)
dc.rights.accessRightsrestricted access
dc.subject.cdu546
dc.subject.keywordPalladium(II) complexes
dc.subject.keywordPyrazolylpyridine ligands
dc.subject.keywordX-ray structure
dc.subject.keywordSupramolecular architecture
dc.subject.ucmQuímica inorgánica (Química)
dc.subject.ucmMineralogía (Geología)
dc.subject.unesco2303 Química Inorgánica
dc.subject.unesco2506.11 Mineralogía
dc.titleMolecular architectures of cationic [Pd(g3 -C3H5)(pzbp2py)]+ complexes and BF 4 and CF3SO 3 as counteranions (pzbp2py = 2-[3,5-bis(4-butoxyphenyl)pyrazol-1-yl]pyridine)
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number691
dspace.entity.typePublication
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