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Trifluoroacetic anhydride promoted tandem conjugate addition of boronic acids/acetal ring opening

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dc.contributor.authorRoscales García, Silvia
dc.contributor.authorGarcía Csaky, Aurelio
dc.date.accessioned2025-01-16T12:28:49Z
dc.date.available2025-01-16T12:28:49Z
dc.date.issued2012
dc.description.abstractA new stereoselective tandem reaction consisting of the metal-free conjugate addition of boronic acids followed by an intramolecular ring opening of a cyclic acetal has been disclosed. Optically pure polysubstituted tetrahydropyrans have been synthesized diastereoselectively by this new reaction. Two new C–C bonds and up to three stereocenters are formed in a single step, allowing the generation of quaternary stereocenters.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyInstituto Pluridisciplinar (IP)
dc.description.refereedTRUE
dc.description.statuspub
dc.identifier.doi10.1021/ol300272j
dc.identifier.officialurlhttps://pubs.acs.org/doi/10.1021/ol300272j
dc.identifier.urihttps://hdl.handle.net/20.500.14352/114679
dc.issue.number5
dc.journal.titleOrganic Letters
dc.language.isoeng
dc.page.final1189
dc.page.initial1187
dc.rights.accessRightsrestricted access
dc.subject.cdu547
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco2306 Química Orgánica
dc.titleTrifluoroacetic anhydride promoted tandem conjugate addition of boronic acids/acetal ring opening
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number14
dspace.entity.typePublication
relation.isAuthorOfPublicationef4f93d7-a007-4514-9055-f8ba8c41138d
relation.isAuthorOfPublication20fb9911-4424-43a0-ad98-890ff7a6dacd
relation.isAuthorOfPublication.latestForDiscoveryef4f93d7-a007-4514-9055-f8ba8c41138d

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