Trifluoroacetic anhydride promoted tandem conjugate addition of boronic acids/acetal ring opening
| dc.contributor.author | Roscales García, Silvia | |
| dc.contributor.author | García Csaky, Aurelio | |
| dc.date.accessioned | 2025-01-16T12:28:49Z | |
| dc.date.available | 2025-01-16T12:28:49Z | |
| dc.date.issued | 2012 | |
| dc.description.abstract | A new stereoselective tandem reaction consisting of the metal-free conjugate addition of boronic acids followed by an intramolecular ring opening of a cyclic acetal has been disclosed. Optically pure polysubstituted tetrahydropyrans have been synthesized diastereoselectively by this new reaction. Two new C–C bonds and up to three stereocenters are formed in a single step, allowing the generation of quaternary stereocenters. | |
| dc.description.department | Depto. de Química Orgánica | |
| dc.description.faculty | Instituto Pluridisciplinar (IP) | |
| dc.description.refereed | TRUE | |
| dc.description.status | pub | |
| dc.identifier.doi | 10.1021/ol300272j | |
| dc.identifier.officialurl | https://pubs.acs.org/doi/10.1021/ol300272j | |
| dc.identifier.uri | https://hdl.handle.net/20.500.14352/114679 | |
| dc.issue.number | 5 | |
| dc.journal.title | Organic Letters | |
| dc.language.iso | eng | |
| dc.page.final | 1189 | |
| dc.page.initial | 1187 | |
| dc.rights.accessRights | restricted access | |
| dc.subject.cdu | 547 | |
| dc.subject.ucm | Química orgánica (Química) | |
| dc.subject.unesco | 2306 Química Orgánica | |
| dc.title | Trifluoroacetic anhydride promoted tandem conjugate addition of boronic acids/acetal ring opening | |
| dc.type | journal article | |
| dc.type.hasVersion | VoR | |
| dc.volume.number | 14 | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | ef4f93d7-a007-4514-9055-f8ba8c41138d | |
| relation.isAuthorOfPublication | 20fb9911-4424-43a0-ad98-890ff7a6dacd | |
| relation.isAuthorOfPublication.latestForDiscovery | ef4f93d7-a007-4514-9055-f8ba8c41138d |
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