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Transition-Metal-Free Reactions of Boronic Acids: 1,3-Stereochemical Induction in the Substrate-Controlled Conjugate Addition

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dc.contributor.authorRoscales García, Silvia
dc.contributor.authorMaroto Ortega, Víctor Manuel
dc.contributor.authorGarcía Csaky, Aurelio
dc.date.accessioned2025-01-27T08:37:21Z
dc.date.available2025-01-27T08:37:21Z
dc.date.issued2013
dc.description.abstractThe substrate-controlled 1,3-stereoselective conjugate addition of boronic acids and potassium trifluoroborates under metal-free conditions has been developed. This reaction affords bicyclic acetals, which have been used as key intermediates in the stereodivergent synthesis of polysubstituted tetrahydropyrans.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyInstituto Pluridisciplinar (IP)
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia e Innovación (España)
dc.description.statuspub
dc.identifier.citationRoscales, Silvia, et al. «Transition-Metal-Free Reactions of Boronic Acids: 1,3-Stereochemical Induction in the Substrate-Controlled Conjugate Addition». The Journal of Organic Chemistry, vol. 78, n.o 24, diciembre de 2013, pp. 12825-30. DOI.org (Crossref), https://doi.org/10.1021/jo402262m.
dc.identifier.doi10.1021/jo402262m
dc.identifier.officialurlhttps://doi.org/10.1021/jo402262m
dc.identifier.urihttps://hdl.handle.net/20.500.14352/116154
dc.journal.titleThe Journal of Organic Chemistry
dc.language.isoeng
dc.page.final12830
dc.page.initial12825
dc.publisherAmerican Chemical Society
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN//CTQ-2010-16170
dc.rights.accessRightsrestricted access
dc.subject.cdu547
dc.subject.keywordBoronic acids
dc.subject.keywordTransition-metal-free reactions
dc.subject.ucmQuímica orgánica (Química)
dc.subject.ucmQuímica orgánica (Farmacia)
dc.subject.unesco23 Química
dc.titleTransition-Metal-Free Reactions of Boronic Acids: 1,3-Stereochemical Induction in the Substrate-Controlled Conjugate Addition
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number78
dspace.entity.typePublication
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relation.isAuthorOfPublication8856e44e-3899-4353-9e20-70fb1a80fa8a
relation.isAuthorOfPublication20fb9911-4424-43a0-ad98-890ff7a6dacd
relation.isAuthorOfPublication.latestForDiscoveryef4f93d7-a007-4514-9055-f8ba8c41138d

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