Aviso: para depositar documentos, por favor, inicia sesión e identifícate con tu cuenta de correo institucional de la UCM con el botón MI CUENTA UCM. No emplees la opción AUTENTICACIÓN CON CONTRASEÑA
 

Electroosmosis through a cation-exchange membrane: Effect of an ac perturbation on the electroosmotic flow

dc.contributor.authorBarragán García, Vicenta María
dc.contributor.authorRuiz Bauzá, Carlos
dc.date.accessioned2023-06-20T18:43:15Z
dc.date.available2023-06-20T18:43:15Z
dc.date.issued2000-10-15
dc.description© 2000 by Academic Press. Financial support from the University Complutense of Madrid under Project PR49/98-7756 is gratefully acknowledged.
dc.description.abstractElectroosmosis experiments through a cation-exchange membrane have been performed using NaCl solutions in different experimental situations. The influence of an alternating (ac) sinusoidal perturbation, of known angular frequency and small amplitude, superimposed to the usual applied continuous (dc) signal on the electroosmotic Row has been studied. The experimental results show that the presence of the ac perturbation affects the electroosmotic flow value, depending on the frequency of the ac signal and on the solution stirring conditions. In the frequency range studied, two regions have been observed where the electroosmotic Row reaches a maximum value: one at low frequencies (similar to Hz); and another at frequencies of the order of kHz. These regions could be related to membrane relaxation phenomena.
dc.description.departmentDepto. de Estructura de la Materia, Física Térmica y Electrónica
dc.description.facultyFac. de Ciencias Físicas
dc.description.refereedTRUE
dc.description.sponsorshipUniversidad Complutense de Madrid
dc.description.statuspub
dc.eprint.idhttps://eprints.ucm.es/id/eprint/21072
dc.identifier.doi10.1006/jcis.2000.7063
dc.identifier.issn0021-9797
dc.identifier.officialurlhttp://dx.doi.org/10.1006/jcis.2000.7063
dc.identifier.relatedurlhttp://pdn.sciencedirect.com/
dc.identifier.urihttps://hdl.handle.net/20.500.14352/58425
dc.issue.number2
dc.journal.titleJournal of Colloid and Interface Science
dc.language.isoeng
dc.page.final366
dc.page.initial359
dc.publisherAcademic Press Inc Elsevier Science
dc.relation.projectIDPR49/98-7756
dc.rights.accessRightsrestricted access
dc.subject.cdu536
dc.subject.keywordCellulose-Acetate Membranes
dc.subject.keywordImpedance
dc.subject.keywordPermeability
dc.subject.keywordDependence
dc.subject.keywordPhases
dc.subject.keywordWater.
dc.subject.ucmTermodinámica
dc.subject.unesco2213 Termodinámica
dc.titleElectroosmosis through a cation-exchange membrane: Effect of an ac perturbation on the electroosmotic flow
dc.typejournal article
dc.volume.number230
dcterms.references1. Prigogine, I., “Introduction to thermodynamics of irreversible processes,” 3rd ed. Wiley, New York, 1968. 2. De Groot, S. R., “Thermodynamics of irreversible processes,” 4th ed. North Holland Publishing Co., Amsterdam, 1966. 3. Demish, H. U., and Pusch, W., J. Colloid Interface Sci. 76, 464 (1980). 4. Tasaka, M., Tamura, S., and Takemura, N., J. Membr. Sci. 12, 169 (1982). 5. Haase, R., and Harff, K., J. Membr. Sci. 12, 279 (1983). 6. Reynard, J. M., Larchet, C., Buluestre, G., and Auclair, B., J. Membr. Sci. 67, 57 (1992). 7. Gavach, C., Pamboutzoglou, G., Nedyalkov, M., and Pourcelly, G., J. Membr. Sci. 45, 37 (1989). 8. Soj rensen, T. S., J. Colloid Interface Sci. 168, 437 (1994). 9. Ledjeff, K., Hahtendorf, F., Peinecke, V., and Heinzel A., Electrochim. Acta 40, 315 (1995). 10. Mafé, S., and Ramírez, P., Acta Polym. 48, 234 (1997). 11. Holdik, H., Alcaraz, A., Ramírez, P., and Mafé, S., J. Electroanal. Chem. 442, 13 (1998). 12. Plesner, I. W., Malmgren-Hansen, B., and Soj rensen, T. S., J. Chem. Soc. Faraday Trans. 90, 2381 (1994). 13. Malmgren-Hansen, B., Soj rensen, T. S., Jensen, J. B., and Hennenberg, M., J. Colloid Interface Sci. 130, 359 (1989). 14. Coster, H. G. L., and Chilcott, T. C., in “Surface Chemistry and Electrochemistry of Membranes,” Chap. 19. Dekker, New York, 1999. 15. Zholkovskij, E. K., in “Surface Chemistry and Electrochemistry of Membranes,” Chap. 2. Dekker, New York, 1999. 16. Ruiz-Bauzá, C., and Rueda-Sánchez, C., J. Non-Equilibr. Thermodyn. 15, 281 (1990). 17. Janz, G. J., in “Reference Electrodes,” Chap. 4. Academic Press, London, 1961. 18. Rubistein, I., and Shtilman, L., J. Chem. Soc. Faraday Trans. 2 75, 231 (1979). 19. Tanaka, Y., J. Membr. Sci. 57, 217 (1991). 20. Barragán, V. M., Ruiz-Bauzá, C., and Mengual, J. I., J. Membr. Sci. 95, 1 (1994). 21. Barragán, V. M., Ruiz-Bauzá, C., and Mengual, J. I., J. Collid Interface Sci. 168, 458 (1994). 22. Böttcher, C. J. F., and Bordewijk, P., “Theory of Electric Polarization,” Vol. 2. Elsevier, New York, 1996. 23. Maxwell, J. C., “A Treatise of Electricity and Magnetism.” Dover, New York, 1954. 24. Wagner, K. W., Arch. Electrotech. 2, 371 (1914). 25. Wagner, K. W., Arch. Electrotech. 3, 67 (1914). 26. Lakshminarayanaiah, W., “Transport Phenomena in Membranes.” Academic Press, New York, 1969. 27. Zumbusch, P.V.,Kulcke,W., and Brunner, G., J. Membr. Sci. 142, 75 (1998)
dspace.entity.typePublication
relation.isAuthorOfPublicationd2c307ae-39ce-419e-a520-2e71b0d84e09
relation.isAuthorOfPublication.latestForDiscoveryd2c307ae-39ce-419e-a520-2e71b0d84e09

Download

Original bundle

Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
barragan27.pdf
Size:
105.11 KB
Format:
Adobe Portable Document Format

Collections