Synthesis of polycyclic aromatic hydrocarbons decorated by fluorinated carbon acids/carbanions

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dc.contributor.authorHoshikawa, Shoki
dc.contributor.authorYanai, Hikaru
dc.contributor.authorMartín‐Mejías, Irene
dc.contributor.authorLázaro Milla, Carlos
dc.contributor.authorAragoncillo Abanades, Cristina
dc.contributor.authorAlmendros Requena, Pedro
dc.contributor.authorMatsumoto, Takashi
dc.date.accessioned2024-01-08T14:21:40Z
dc.date.available2024-01-08T14:21:40Z
dc.date.issued2021
dc.description.abstractThe carboarylation reaction of biphenyl‐alkynes was successfully triggered by electrophilic attack of 1,1‐bis(triflyl)ethylene on the alkyne moiety to give polycyclic aromatic hydrocarbons (PAHs) decorated by superacidic carbon acid functionality. Neutralisation of thus obtained acids with NaHCO3 yielded the corresponding sodium salts, which showed improved solubility in both aqueous and organic solvents.
dc.description.departmentDepto. de Química Orgánica
dc.description.facultyFac. de Ciencias Químicas
dc.description.refereedTRUE
dc.description.sponsorshipMinisterio de Ciencia e Innovación (España)
dc.description.sponsorshipEuropean Commission
dc.description.statuspub
dc.identifier.citationHoshikawa S, Yanai H, Martín-Mejías I, Lázaro-Milla C, Aragoncillo C, Almendros P, Matsumoto T. Synthesis of Polycyclic Aromatic Hydrocarbons Decorated by Fluorinated Carbon Acids/Carbanions, 2021, 27, 16112-16116.
dc.identifier.doi10.1002/chem.202103188
dc.identifier.essn1521-3765
dc.identifier.issn0947-6539
dc.identifier.officialurlhttps://doi.org/10.1002/chem.202103188
dc.identifier.urihttps://hdl.handle.net/20.500.14352/91828
dc.issue.number65
dc.journal.titleChemistry a European Journal
dc.language.isoeng
dc.page.final16116
dc.page.initial16112
dc.publisherWiley-VCH GmbH
dc.rights.accessRightsrestricted access
dc.subject.cdu547
dc.subject.keywordPolycyclic
dc.subject.keywordAromatic
dc.subject.keywordFluorinated
dc.subject.ucmQuímica orgánica (Química)
dc.subject.unesco2306 Química Orgánica
dc.subject.unesco2306.02 Hidrocarburos Aromáticos
dc.titleSynthesis of polycyclic aromatic hydrocarbons decorated by fluorinated carbon acids/carbanions
dc.typejournal article
dc.type.hasVersionVoR
dc.volume.number27
dspace.entity.typePublication
relation.isAuthorOfPublication6ddf42bc-c237-4feb-bc28-f9c7484ed291
relation.isAuthorOfPublication8b257537-0758-463d-9e75-ac1e3d55f9a6
relation.isAuthorOfPublicationee8363b4-4019-453d-abd3-6258ecc4299f
relation.isAuthorOfPublication.latestForDiscovery8b257537-0758-463d-9e75-ac1e3d55f9a6
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