Synthesis of Di(hetero)arylamines from Nitrosoarenes and Boronic Acids: A General, Mild, and Transition-Metal-Free Coupling

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https://pubs.acs.org/doi/10.1021/acs.orglett.8b00473

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2018

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https://hdl.handle.net/20.500.14352/125553

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Synthesis of Di(hetero)arylamines from Nitrosoarenes and Boronic Acids: A General, Mild, and Transition-Metal-Free Coupling Silvia Roscales and Aurelio G. Csákÿ Organic Letters 2018 20 (6), 1667-1671 DOI: 10.1021/acs.orglett.8b00473

Abstract

The synthesis of di(hetero)arylamines by a transition-metal-free cross-coupling between nitrosoarenes and boronic acids is reported. The procedure is experimentally simple, fast, mild, and scalable and has a wide functional group tolerance, including carbonyls, nitro, halogens, free OH and NHgroups. It also permits the synthesis of sterically hindered compounds.

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Química orgánica (Química)

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2306 Química Orgánica

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